Process for making low crystallinity polyolefins
AssigneeHercules Incorporated
InventorJohn H. Johnson
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Abstract
Disclosed is a solution polymerization process for obtaining high yields of high molecular weight, low crystallinity polymers of propylene and higher 1-olefins at low catalyst levels. The polymerization is carried out using a catalyst system containing a soluble transition metal component derived from magnesium carboxylate and a salt of titanium, zirconium or hafnium, and specified alkyl aluminum halide activators.
Claims17
A process for the production of high molecular weight polyolefins having a degree of crystallinity less than about 25%, which process comprises polymerizing at least one 1-olefin containing at least 3 carbon atoms or a mixture of at least one of said olefins with up to about 67 weight % of ethylene in an inert liquid hydrocarbon diluent at a temperature ranging from about 25.degree. C. to about 90.degree. C. in the presence of a catalytic amount of a catalyst system consisting essentially of
- (a) a hydrocarbon soluble transition metal component derived by contacting in an inert liquid hydrocarbon
- (1) a soluble, halide free magnesium-carboxylate having the general formula Mg(OOCR').sub.2 where each R' is alike or different and is derived from a carboxylic acid containing at least 2 carbon atoms with
- (2) a soluble salt of a transition metal selected from the group consisting of tetravalent titanium, zirconium and hafnium, and
- (b) an alkylaluminum halide activator having the general formula R.sub.n AlX.sub.3-n where R is a 1 to 18 carbon alkyl group and n is a number from 1.5 to 2.5,
- the molar ratio of transition metal salt to magnesium carboxylate being 0.003 to 3, the molar ratio of alkylaluminum halide activator to transition metal salt being at least 1 and the molar ratio of alkylaluminum halide activator to magnesium carboxylate being greater than 2.5.
Dependencies are inferred from the claim text.