Phenylalkylamino-styryl dyestuffs
AssigneeBayer Aktiengesellschaft
InventorHermann Beecken
Life of this patent
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Abstract
Cationic styryl dyestuffs of the formula ##STR1## in which A.sup.1 is an alkyleneoxy or alkyleneamino radical, D.sup.1 is a direct bond or divalent radical, An is an anion, and the terminal phenyl ring is unsubstituted or substituted by CN, alkyl or alkoxy. The compounds are suitable for dyeing, enscribing and printing paper for dyeing and printing synthetic fibres, especially made of polyacrylonitrile, acid-modified polyesters or polyamides.
Claims8
Cationic styryl dyestuff of the formula ##STR184## wherein R'.sub.2 denotes C.sub.1 -C.sub.4 -alkyl, or benzyl or .alpha.- or .beta.-phenylethyl unsubstituted or substituted by 1-2 chlorine, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy groups, or cyclopentyl or cyclohexyl unsubstituted or substituted by 1-2 C.sub.1 -C.sub.4 -alkyl groups,
- R'.sub.3 denotes hydrogen or C.sub.1 -C.sub.4 -alkyl and
- R'.sub.4 denotes C.sub.1 -C.sub.4 -alkyl, or
- R'.sub.2, R'.sub.3 and R'.sub.4 together with the nitrogen atom to which they are bonded form imidazole or pyridine which is unsubstituted or substituted by 1 or 2 C.sub.1 -C.sub.4 -alkyl groups, or
- R'.sub.3 and R'.sub.4 together with the nitrogen atom to which they are bonded form piperidine, pyrrolidine, morpholine, piperazine or hexamethyleneimine which is unsubstituted or substituted by 1-4 C.sub.1 -C.sub.4 -alkyl groups,
- R'.sub.5 denotes C.sub.1 -C.sub.4 -alkyl, or phenyl, benzyl or .alpha.- or .beta.-phenylethyl unsubstituted or substituted by 1-2 chlorine, cyano, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy groups, R.sub.9 denotes hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or chlorine and
- R.sub.10 denotes hydrogen or C.sub.1 -C.sub.4 -alkoxy, or
- R'.sub.5 and R.sub.10 together with the benzene ring and the nitrogen atom to which R'.sub.5 is bonded form an indoline, tetrahydroquinoline or 2,3-dihydro-1,4-benzoxazine radical which is unsubstituted or substituted in the heterocyclic part by 1-4 C.sub.1 -C.sub.4 -alkyl or phenyl, or form a carbazole, phenoxazine or phenthiazine radical which is unsubstituted or substituted by 1-2 C.sub.1 -C.sub.4 -alkyl,
- A' denotes ##STR185## which link via the hetero-atom to the CO group, R.sub.11 denotes hydrogen, C.sub.1 -C.sub.4 -alkyl or phenyl which is unstituted or substituted by 1-2 chlorines or C.sub.1 -C.sub.4 -alkyls,
- D' denotes a direct bond or ##STR186## in which m is 0-4,
- n is 1-4,
- p is 1-4 and
- X.sub.1 is O, S, SO.sub.2, COO, OCO, NR.sub.6 --CO, CO--NR.sub.6, NR.sub.6 --SO.sub.2, SO.sub.2 --NR.sub.6, NCOR.sub.7, NHCONH, OCO--NH, NH--COO, OCO--CH.sub.2 --S, OCO--CH.dbd.CH or OCO--CH.sub.2 O,
- R.sub.6 is H, CH.sub.3, C.sub.2 H.sub.5, allyl or benzyl;
- R.sub.7 is H or CH.sub.3 ;
- and
- An.sup..crclbar. represents an anion,
- and wherein the abovementioned alkyl radicals are unsubstittuted or substituted by 1-2 chlorine, cyano, C.sub.1 -C.sub.4 -alkoxy, phenoxy, naphthoxy, benzyloxy, benzoyloxy, allyloxy, C.sub.1 -C.sub.4 -alkylcarbonyloxy or C.sub.1 -C.sub.4 -alkoxycarbonyl groups, and the phenyl groups, in turn, are unsubstituted or substituted by 1-2 cyano or C.sub.1 -C.sub.4 alkoxy groups.
A dye represented by the structure ##STR195## where R.sub.1 is C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkyl substituted by one cyano,
- D is --CH.sub.2 --,
- E is phenyl,
- R.sub.9 is hydrogen,
- R.sub.10 is hydrogen or methyl,
- R.sub.1, R.sub.2 and R.sub.3 are each methyl or together with the nitrogen to which they are bonded form pyridine or R.sub.1 is methyl and R.sub.2 and R.sub.3 together with the nitrogen atom to which they are bonded form morpholine, and
- A is an anion.
A dye represented by the structure ##STR196## where A is an anion.
A dye represented by the structure ##STR198## where A is an anion.
Dependencies are inferred from the claim text.