Fluoroaliphatic radical-containing, substituted guanidines and fibrous substrates treated therewith
AssigneeMinnesota Mining and Manufacturing Company
InventorsJohn C. Chang, Richard D. Howells
Life of this patent
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Abstract
Novel fluoroaliphatic radical-containing, substituted guanidines useful in the form of organic solutions or aqueous dispersions in the treatment of fibrous substrates, such as textile fibers, to impart oil and water repellency.
Claims17
Normally solid, water-insoluble, fluorochemical guanidine compositions which are fluoroaliphatic radical-containing, substituted guanidine compounds, or compositions comprising mixtures thereof, said compounds having one or more monovalent fluoroaliphatic radicals having at least three fully fluorinated carbon atoms and one or more substituted guanidino moieties of the formula ##STR18## said radicals and moieties being bonded together by linking groups selected from aliphatic, aromatic, oxy, thio, carbonyl, sulfone, sulfoxy, --N(CH.sub.3)--, sulfonamido, carbonamido, sulonamidoalkylene, carbonamidolkylene, carbonyloxy, urethane, urea, and combinations thereof, with the proviso that when only one guanidino moiety is present, and only two organic substituents are in said guanidino moiety, said substituents must be on different nitrogen atoms of the moiety, and when more than one guanidine moiety is present, said moieties are bonded together by divalent linking groups selected from the group consisting of alkylene, aralkylene, arylene, polyoxyalkylene, and combinations thereof and can contain said fluoroaliphatic radical.
A fluorochemical guanidine represented by the formula ##STR19## where R--Q is C.sub.8 F.sub.17 SO.sub.2 N(C.sub.2 H.sub.5)C.sub.2 H.sub.4 OCONH--, A is --C.sub.6 H.sub.4 CH.sub.2 C.sub.6 H.sub.4--, ##STR20## is --N(C.sub.4 H.sub.9).sub.2, and n is 2.
A fluorochemical guanidine represented by the formula ##STR21## where R--Q is C.sub.8 F.sub.17 SO.sub.2 N(C.sub.2 H.sub.5)C.sub.2 H.sub.4 OCONH--, A is --C.sub.6 H.sub.4 CH.sub.2 C.sub.6 H.sub.4 --, R.sup.2 --N--R.sup.2 is ##STR22## and n is 1 to 6.
A fluorochemical guanidine represented by the formula ##STR23## where R--Q is C.sub.8 F.sub.17 SO.sub.2 N(C.sub.2 H.sub.5)C.sub.2 H.sub.4 OCONH--, A is --C.sub.6 H.sub.4 CH.sub.2 C.sub.6 H.sub.4, R.sup.2 --N--R.sup.2 is --N(iso--C.sub.3 H.sub.7).sub.2, and n is 1 to 6.
A fluorochemical guanidine represented by the formula ##STR24## where R--Q is C.sub.8 F.sub.17 SO.sub.2 N(C.sub.2 H.sub.5)C.sub.2 H.sub.4 OCONH--, A is --CH.sub.2 C.sub.6 H.sub.4 CH.sub.2 --, R.sup.2 --N--R.sup.2 is --N(C.sub.4 H.sub.9).sub.2, and n is 1 to 6.
A fluorochemical guanidine represented by the formula ##STR25## where R--Q is C.sub.8 F.sub.17 SO.sub.2 N(C.sub.2 H.sub.5)C.sub.2 H.sub.4 OCONH--, A is --CH.sub.2 C.sub.6 H.sub.4 CH.sub.2 --, R.sup.2 --N--R.sup.2 is ##STR26## and n is 1 to 6.
A fluorochemical guanidine represented by the formula ##STR27## where R--Q is C.sub.8 F.sub.17 SO.sub.2 N(C.sub.2 H.sub.5)C.sub.2 H.sub.4 OCONH--, A is --CH.sub.2 C.sub.6 H.sub.4 CH.sub.2 --, R.sup.2 --N--R.sup.2 is --N(iso--C.sub.3 H.sub.7).sub.2, and n is 1 to 6.
Normally solid, water-insoluble, fluorochemical guanidine compositions which are fluoroaliphatic radical-containing substituted guanidine compounds or compositions comprising a mixture of such compounds, said compounds being represented by the general formula ##STR28## where n is 0 to 20, x is 0 to 1, R.sup.1 and R.sup.2 are hydrogen atoms, a monovalent fluoroaliphatic radical, R.sub.f, having at least three fully fluorinated carbon atoms, or an organic radical selected from the group consisting of alkyl, cycloalkyl, aryl, and combinations thereof, A is a divalent linking group selected from the group consisting of alkylene, aralkylene, arylene polyoxyalkylene, and combinations thereof, which can contain said R.sub.f, and Q is a divalent hetero atom-containing or organic linking group selected from the group consisting of aliphatic aromatic aralkyl, fluoroaliphatic, and combinations thereof, with the proviso that at least one fluoroaliphatic radical, R.sub.f, is present in one or more of the R.sup.1, R.sup.2, and A groups, that where R.sup.1 or R.sup.2 is R.sub.f, x is 1, and that when only one guanidino moiety is present and only two organic substituents are in said guanidino moiety, said substituents must be on different nitrogen atoms.
Dependencies are inferred from the claim text.