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US 4,539,397 AGranted
(Alkoxydiazo)halobenzeneacetonitriles
AssigneeEthyl Corporation
InventorVenkataraman Ramachandran
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Abstract
The coupling of an aminohalobenzeneacetonitrile with a benzene compound in the presence of an alkyl nitrite to form a halobiphenylacetonitrile via a diazo intermediate is improved by conducting the reaction at a temperature of about 0.degree.-15.degree. C. until diazotization of the aminohalobenzeneacetonitrile is substantially complete. Use of the low diazotization temperature leads to an increased yield of halobiphenylacetonitrile.
Claims2
A diazo compound corresponding to the formula:
- ##STR4## wherein R is hydrogen or an alkyl group, R' is an alkyl group, and X is halo.
A diazo compound corresponding to the formula:
- ##STR5## wherein R' is an alkyl group of 1-6 carbons.
Dependencies are inferred from the claim text.