Phosphorus-containing compounds, their production and their use as antioxidants
AssigneeSumitomo Chemical Company, Limited
InventorsYukoh Takahashi, Shinichi Yachigo, Tamaki Ishii
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AssigneeSumitomo Chemical Company, Limited
InventorsYukoh Takahashi, Shinichi Yachigo, Tamaki Ishii
Estimating the term…
Phosphorus-containing compounds of the formula: ##STR1## wherein R.sup.1 and R.sup.2 are each a hydrogen atom or a lower alkyl group, and R.sup.3 is a lower alkyl or phenyl group. These compounds may be used as stabilizers against the action of heat, light and oxygen for organic substances and especially polyolefin resins. These phosphorus-containing compounds may be used in conjunction with other stabilizers such phenol-type and sulfur-containing antioxidants, especially in polyolefin resin compositions to produce a polyolefin resin composition having excellent resistance to light, heat and oxygen. The present invention also relates to a method of producing the compounds of the aforementioned formula by reacting ##STR2## with a disubstituted phosphonate of the formula ##STR3## wherein R.sup.1, R.sup.2 and R.sup.3 are as defined above.
A phosphorus-containing compound represented by the formula (1), ##STR7## wherein R.sup.1 and R.sup.2 are each a hydrogen atom or a lower alkyl group, and R.sup.3 is a lower alkyl or phenyl group.
A polyolefin resin composition characterized in that said composition contains phosphorus-containing, phenol-type and sulfur-containing antioxidants in amounts of 0.01 to 5 parts by weight, 0.005 to 2 parts by weight and 0 to 5 parts by weight, respectively, based on 100 parts by weight of polyolefin resin, and said phosphorus-containing antioxidant is a phosphonate represented by the formula (I), ##STR8## wherein R.sup.1 and R.sup.2 are each a hydrogen atom or a lower alkyl group, and R.sup.3 is a lower alkyl or phenyl group.
Dependencies are inferred from the claim text.