Expandable thermoplastic resin particles and process for preparing the same
AssigneeKanegafuchi Kagaku Kogyo Kabushiki Kaisha
InventorsKiyoshi Mori, Masao Nakagawa
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Abstract
Expandable thermoplastic resin particles having excellent heat resistance, solvent resistance, foamability and moldability comprising a copolymer of 10 to 80% by weight of .alpha.-methylstyrene, 5 to 50% by weight of acrylonitrile and 0 to 70% by weight of at least one member selected from the group consisting of styrene, methyl methacrylate, vinyl toluene and t-butylstyrene, and an expanding agent impregnated in the copolymer, prepared easily in high conversions by an aqueous suspension polymerization using particular difunctional organic peroxides, preferably those capable of producing t-butoxy radicals, followed by impregnation of the produced polymer particles with the expanding agent.
Claims9
An expandable thermoplastic resin particle comprising a thermoplastic resin and 2 to 15% by weight of an expanding agent, said thermoplastic resin being prepared by suspension-polymerizing 10 to 80% by weight of .alpha.-methylstyrene, 5 to 50% by weight of acrylonitrile and 0 to 70% by weight of at least one other monomer selected from the group consisting of styrene, methyl methacrylate, vinyl toluene and t-butystyrene in the presence of a difunctional organic peroxide as an initiator at a temperature of 80.degree. to 130.degree. C.
A process for preparing expandable thermoplastic resin particles which comprises suspension-polymerizing 10 to 80% by weight of .alpha.-methylstyrene, 5 to 50% by weight of acrylonitrile and 0 to 70% by weight of at least one other monomer selected from the group consisting of styrene, methyl methacrylate, vinyl toluene and t-butylstyrene in the presence of a difunctional organic peroxide as an initiator at a temperature of 80.degree. to 130.degree. C., and impregnating an expanding agent in the produced polymer particles during or after the polymerization.
Dependencies are inferred from the claim text.