Amine oxide compounds
AssigneeCiba-Geigy Corporation
InventorLeonardo Guglielmetti
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AssigneeCiba-Geigy Corporation
InventorLeonardo Guglielmetti
Estimating the term…
Novel amine oxide compounds of the formula ##STR1## in which m is the integer 1 or 2, A is a through-conjugated radical of a fluorescent brightener system, which radical contains unsubstituted or non-chromophorically substituted aromatic carbocyclic and/or heterocyclic rings, X is a direct bond between A and Y, an oxygen atom or sulfur atom or a group of the formula --SO.sub.2 --, --SO.sub.2 --O--, --COO--, --CON(R)-- or --SO.sub.2 N(R)--, in which R is hydrogen or unsubstituted or non-chromophorically substituted alkyl, Y is an unsubstituted or non-chromophorically substituted straight-chain or branched alkylene or alkyleneoxyalkylene group, and R.sub.1 and R.sub.2 independently of one another are cycloalkyl, unsubstituted or non-chromophorically substituted alkyl or phenyl, or R.sub.1 and R.sub.2, together with the nitrogen atom to which they are bonded, are a 5-membered or 6-membered saturated or unsaturated heterocyclic ring which can additionally contain one or two further hetero-atoms as ring members, and which can be substituted further, or, if X is a group of the formula --CON(R)-- or --SO.sub.2 N(R)-- and Y is ethylene or propylene, R and R.sub.1 together are an ethylene or methylene group, thereby forming a corresponding saturated heterocyclic ring containing 2 nitrogen atoms. The novel amine oxide compounds can be prepared, for example, by oxidizing the corresponding amino compounds with per-compounds. They can be used as fluorescent brighteners, especially for brightening cellulose in a washing liquor. The brighteners exhibit particularly advantageous properties when used in liquid detergents containing cationic textile softeners.
An amine oxide compound of the formula ##STR53## in which m is 1 or 2, A is a brightener radical selected from the group consisting of the 4,4'-distyrylbiphenyls, 4,4'-divinyl-stilbenes and 1,4-distyrylbenzenes, which are unsubstituted or substituted by 1-4 substituents selected from halogen, alkyl, hydroxyalkyl, halogenoalkyl, cyanoalkyl, alkoxyalkyl, phenylalkyl, carboxyalkyl, carbalkoxyalkyl, alkenyl, cycloalkyl, alkoxy, alkenyloxy, alkoxycarbonyl, carbamoyl, cyano, alkylsulfonyl, phenylsulfonyl, alkyloxysulfonyl, sulfamoyl, hydroxyl, carboxyl, sulfo and trifluoromethyl, X is a direct bond between A and Y, an oxygen atom or sulfur atom or a group of the formula --SO.sub.2 --, --SO.sub.2 --O--, --COO--, --CON(R)-- or --SO.sub.2 N(R)--, in which R is hydrogen, alkyl or alkyl substituted by halogen, cyano, hydroxyl, C.sub.2 -C.sub.5 -carbalkoxy, C.sub.1 -C.sub.4 -alkoxy, phenyl, chlorophenyl, methylphenyl, methoxyphenyl, carbamoyl or sulfamoyl, Y is alkylene or alkyleneoxyalkylene or either of said groups substituted by halogen, hydroxyl, C.sub.2 -C.sub.5 -carbalkoxy, C.sub.1 -C.sub.4 -alkoxy, phenyl, chlorophenyl, methylphenyl, methoxyphenyl, carbamoyl or sulfamoyl, and R.sub.1 and R.sub.2 independently of one another are cycloalkyl, alkyl or phenyl, or alkyl substituted by halogen, hydroxy, C.sub.2 -C.sub.5 -carbalkoxy, C.sub.1 -C.sub.4 -alkoxy, phenyl, chlorophenyl, methylphenyl, methoxyphenyl, carbamoyl or sulfamoyl, wherein in all said carbamoyl or sulfamoyl groups the nitrogen atom is unsubstituted or substituted by 1 or 2 groups chosen from C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -hydroxyalkyl, C.sub.2 -C.sub.5 -cyanoalkyl, C.sub.1 -C.sub.4 -halogenalkyl, benzyl or phenyl.
Dependencies are inferred from the claim text.