Catalysis over activated zeolites
AssigneeMobil Oil Corporation
InventorsJoseph N. Miale, Clarence D. Chang
Life of this patent
Estimating the term…
Abstract
A process is provided for conducting organic compound conversion over a catalyst comprising a crystalline zeolite which has been treated by impregnation with an ammoniacal aluminum fluoride solution, contact with an ammonium salt solution, and calcination.
Claims16
A process for converting a feedstock comprising an alcohol, ether or mixture thereof to conversion products comprising hydrocarbons which comprises contacting said feedstock at conversion conditions with a catalyst comprising a zeolite composition prepared by a method which comprises impregnating a zeolite having an initial silica-to-alumina mole ratio of 70 or more with an ammoniacal aluminum fluoride solution at a temperature of from about 0.degree. C. to about 100.degree. C., said solution comprising from about 0.1 to about 5 weight percent of an aluminum fluoride in solution with at least one member selected from the group consisting of ammonium hydroxide and ammonia, contacting the impregnated zeolite with a warm aqueous 0.1 to 2 Normal solution of an ammonium salt, and calcining the ammonium salt solution contacting material at a temperature of from about 200.degree. C. to about 600.degree. C.
A process for converting a feedstock comprising an alcohol, ether or mixture thereof to conversion products comprising hydrocarbons which comrpises contacting said feedstock at conversion conditions with a catalyst comprising a zeolite composition prepared by a method which comprises impregnating a zeolite having an initial silica-to-alumina mole ratio of 70 or more and the structure of ZSM-5 with an ammoniacal aluminum fluoride solution at a temperature of from about 0.degree. C. to about 100.degree. C., said solution comprising from about 0.1 to about 5 weight percent of an aluminum fluoride in solution with at least one member selected from the group consisting of ammonium hydroxide and ammonia, contacting the impregnated zeolite with a warm aqueous 0.1 to 2 Normal solution of an ammonium salt, and calcining the ammonium salt solution contacted material at a temperature of from about 200.degree. C. to about 600.degree. C.
Dependencies are inferred from the claim text.