Alcohol recovery process
AssigneeExxon Research & Engineering Co.
InventorWilliam D. Diana
Life of this patent
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Abstract
According to the process of this invention, saturated mono-alcohols are recovered from solutions containing such mono-alcohols together with a carboxylic acid extraction solvent therefor by passing the mono-alcohol solution to an alcohol vaporization zone, introducing a substantially anhydrous stripping gas to the alcohol vaporization zone in an amount and under conditions sufficient to form vapors comprising the mono-alcohol and to form an alcohol-depleted liquid phase comprising the carboxylic acid extraction solvent.
Claims30
An improved process for recovering alcohols from acid/alcohol feedstreams comprising aqueous strong acid solutions containing said alcohols which comprises (a) contacting said acid/alcohol feedstream in an extraction zone with an effective amount of an extraction solvent selected from the group consisting of alicyclic and acyclic carboxylic acids having from 6 to 20 carbons per molecule and mixtures thereof, for a time and under conditions sufficient to selectively extract said alcohol from said acid/alcohol feedstream and to form a first liquid phase comprising an alcohol-enriched carboxylic acid extract, and a second liquid phase comprising an aqueous strong acid raffinate depleted in alcohol, (b) introducing said alcohol-enriched carboxylic acid extract into an alcohol vaporization zone and contacting said extract therein with substantially anhydrous stripping vapors, in an amount and under conditions sufficient to form an overhead product comprising at least a majority of said alcohol passed to said vaporization zone and an alcohol-depleted carboxylic acid extraction solvent liquid, (c) recovering said alcohol vapors from said vaporization zone, and (d) recycling said alcohol-depleted carboxylic acid extraction solvent to said extraction zone.
A process for recovering alcohols from acid/alcohol feedstreams comprising aqueous sulfuric acid solutions containing from 40 to 80 wt. % sulfuric acid and containing at least one saturated mono-alcohol having from 3 to 8 carbon atoms per molecule, which comprises (a) contacting said acid/alcohol feedstream in an extraction zone with an effective amount of an extraction solvent selected from the group consisting of neo-acids having from 6 to 20 carbon atoms per molecule for a time and under conditions sufficient to selectively extract said alcohol from said feedstream and to form a first liquid phase comprising an alcohol-enriched carboxylic acid extract containing said alcohol in a concentration of from about 5 to 20 weight percent and a second liquid phase comprising an aqueous sulfuric acid raffinate depleted in alcohol and having a sulfuric acid acid strength of at least 1 wt. % greater than the sulfuric acid acid strength in said acid/alcohol feedstream, (b) introducing said alcohol-enriched carboxylic acid extract to a vaporization zone and contacting said extract therein with a substantially anhydrous stripping gas comprising at least one member selected from the group consisting of N.sub.2, olefins of from 3 to 8 carbon atoms and alkanes of from 3 to 8 carbon atoms, in an amount and under conditions sufficient to form an overhead product comprising at least a majority of said alcohol passed to said vaporization zone alcohol and an alcohol-depleted carboxylic acid extraction solvent liquid having a carboxylic acid concentration of from about 1.01 to 1.15 times greater than the concentration of said carboxylic acid in said alcohol-enriched carboxylic acid extract, (c) recovering said alcohol vapors, and (d) recycling at least a portion of said alcohol-depleted carboxylic acid extraction solvent liquid to said extraction zone.
Dependencies are inferred from the claim text.