Method of storing radioactive wastes using modified tobermorite
AssigneeThe United States of America as represented by the United States Department of Energy
InventorsSridhar Komarneni, Della M. Roy
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Abstract
A new cation exchanger is a modified tobermorite containing aluminum isomorphously substituted for silicon and containing sodium or potassium. The exchanger is selective for lead, rubidium, cobalt and cadmium and is selective for cesium over calcium or sodium. The tobermorites are compatable with cement and are useful for the long-term fixation and storage of radioactive nuclear wastes.
Claims5
A method of fixing metal ions contained in liquid low and intermediate level nuclear wastes for long-term storage comprising:
- contacting the liquid waste with an ion-exchange material which is a modified tobermorite containing aluminum isomorphously substituted for silicon and containing per 100 grams, about 1 to 200 milliequivalents of an alkali metal selected from the group consisting of sodium, potassium and mixtures thereof, whereby the metal ions in the liquid waste are taken up by the ion-exchange material;
- separating the ion-exchange material from the liquid;
- mixing the ion-exchange material containing the ions with portland cement to form a mixture containing up to about 40 weight percent ion-exchange material;
- and
- solidifying the mixture, thereby fixing the ions for long-term storage.
A method of fixing radioactive cesium for long-term storage comprising:
- contacting a solution containing cesium and other metal ions with a modified-tobermorite containing aluminum isomorphously substituted for silicon and containing per 100 grams, about 1 to 200 milliequivalents of an alkali metal selected from the group consisting of sodium, potassium and mixtures thereof, whereby the cesium is taken up by the modified tobermorite;
- separating the tobermorite containing the cesium from the liquid;
- mixing the tobermorite containing the cesium with portland cement to form a mixture containing up to about 40 weight percent tobermorite;
- and
- solidifying the mixture, thereby fixing the cesium ions for long-term storage.
Dependencies are inferred from the claim text.