Process for trichromatic dyeing or printing of polyamide
AssigneeCiba-Geigy Corporation
InventorsHarry Schaetzer, Helmut Raisin, Dieter Mausezahl
Life of this patent
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Abstract
A process for dyeing or printing natural and synthetic polyamide material by the trichromatic technique, which comprises the use of a red dye of the formula (1) defined in the specification, or a mixture of the red dye of the formula (1) with a red dye of the formula (2) together with at least one yellow or orange dye of the formula (3), or a mixture of at least one yellow or orange dye of the formula (3) with a yellow dye of the formula (4) and at least one blue dye of the formula (5). The process of the invention is suitable for dyeing natural or synthetic polyamide material from an aqueous liquor or for printing with printing pastes. It is particularly suitable for dyeing from short liquors.
Claims18
A process for dyeing or printing natural and synthetic polyamide material by the trichromatic technique, which comprises the use of a red dye of the formula ##STR97## wherein A is hydrogen, unsubstituted or substituted C.sub.1 -C.sub.4 alkyl, ##STR98## or --SO.sub.2 R.sub.3, wherein R.sub.1 is C.sub.1 -C.sub.4 alkyl, R.sub.2 is unsubstituted or substituted C.sub.5 -C.sub.7 cycloalkyl or unsubstituted or substituted phenyl, and R.sub.3 is unsubstituted or substituted phenyl or unsubstituted or substituted phenoxy, and B is hydrogen, C.sub.2 -C.sub.4 alkanoylamino, C.sub.5 -C.sub.8 cycloalkoxycarbonylamino, C.sub.1 -C.sub.4 alkoxycarbonylamino, C.sub.1 -C.sub.4 alkylsulfonylamino or unsubstituted or substituted phenylsulfonylamino, or a mixture of the red dye of the formula (1) with a red dye of the formula ##STR99## wherein R.sub.4 is methyl or ethyl and R.sub.5 is cyclohexyl or phenyl, together with at least one yellow or orange dye of the formula ##STR100## wherein B.sub.1, B.sub.2 and E.sub.1 are hydrogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy, and X is straight chain or branched C.sub.1 -C.sub.4 alkyl or straight chain or branched C.sub.2 -C.sub.4 hydroxyalkyl, or a mixture of at least one yellow or orange dye of the formula (3) with a yellow dye of the formula ##STR101## wherein Z.sub.1, Z.sub.2 and Z.sub.3 are each independently hydrogen, halogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy, and at least one blue dye of the formula ##STR102## wherein one Y is hydrogen or methyl and the other Y is C.sub.2 -C.sub.4 alkanoylamino or C.sub.2 -C.sub.4 hydroxyalkylsulfamoyl and Z.sub.4 is hydrogen or methyl.
Dependencies are inferred from the claim text.