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US 4,536,561 AGranted
Thermotropic, wholly aromatic polyesters
AssigneeBayer Aktiengesellschaft
InventorsManfred Schmidt, Hans-Rudolf Dicke
Life of this patent
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Abstract
Thermotropic, wholly aromatic polyesters containing condensed residues of (a) p-hydroxy benzoic acid, (b) 3-chloro-4-hydroxy benzoic acid, (c) isophthalic acid, (d) hydroquinone and (e) 3,4'- and/or 4,4'-dihydroxy-diphenyl, -diphenyl ether and/or -diphenyl sulphide have high rigidity and toughness and yet are easily processable.
Claims3
A thermotropic, wholly aromatic polyester comprising condensed residues of monomeric units (a) through (e) wherein:
- (a) is p-hydroxyl-benzoic acid or p-hydroxyl-benzoic acid substituted in the nucleus by one or two C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy C.sub.6 -C.sub.10 aryl or C.sub.7 -C.sub.12 alkylaryl groups,
- (b) is 3-chloro-4-hydroxy-benzoic acid,
- (c) is isophthalic acid,
- (d) is hydroquinone and
- (e) is selected from 3,4'-dihydroxy-diphenyl, 4,4'-dihydroxydiphenyl, 3,4'-dihydroxy-diphenyl ether, 4,4'-dihydroxy-diphenyl sulphide, and mixtures thereof, wherein said polyester contains the condensed residues of
- (a) at a concentration of from 25 to 65 mol %,
- (b) at a concentration of from 5 to 40 mol %,
- (c) at a concentration of from 30 to 50 mol %, and
- (d) at a concentration of from 1 to 10 mol %,
- each based on the sum of the condensed residues (a), (b) and (c), with the proviso that the sum of concentrations of (a) and (b) amounts to a minimum of 50 mol % and a maximum of 70 mol % and that the molar ratio of the condensed residues c/(d+e) is from 0.95 to 1.05.
7 more elements
Dependencies are inferred from the claim text.