Method of producing potassium magnesium phosphate
AssigneeKali und Salz Aktiengesellschaft
InventorKarl-Richard Loblich
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Abstract
Process for producing potassium magnesium phosphate by reacting basic magnesium compounds with phosphoric acid or phosphates in the presence of potassium sulfate from a mother liquor containing per 1000 g water up to 150 g magnesium sulfate and up to 120 g potassium sulfate. Precipitation forms with addition of calcium oxide or hydroxide equimolar to present magnesium sulfate and after phosphoric acid adjustment of the pH to 2-4, mechanical separation and addition of potassium sulfate and basic magnesium compounds, the desired product results.
Claims13
Process for the production of potassium magnesium phosphate by reacting basic magnesium compound with phosphoric acid or phosphate in the presence of a potassium sulfate excess wherefrom the formed potassium magnesium phosphate is separated from the mother liquor, washed with water and dried, comprising stirring into said mother liquor containing magnesium sulfate and potassium sulfate a free calcium oxidic containing material in amounts corresponding to an equimolar ratio of free calcium oxidic and dissolved magnesium sulfate, thereby producing a turbidity, providing an acid pH in said turbidity, separating the solid phase, stirring in potassium sulfate for formation of potassium magnesium phosphate and for maintenance of in said mother liquor the potassium sulfate content, adjusting the pH- of said reaction mixture basic and separating any crystallizate falling out as product from said mother liquor from said reaction mixture, the said mother liquor is then recycled to the process start.
Dependencies are inferred from the claim text.