Drilling and completion muds useful at elevated temperatures
AssigneeSociete Nationale Elf Aquitaine
InventorLino Vio
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Abstract
The invention is clay based water drilling or completion muds with low viscosity and exceptional stability at elevated temperatures of up to 200.degree. C. The muds are characterized by containing from 1 to 10 grams per liter of a low molecular weight polymer or copolymer having functional groups wherein from 2 to 95% of the functional groups consist independently of hydroxamic or thiohydroxamic groups. The mud composition comprises (a) fresh water, water containing electrolytes such as sodium chloride, potassium chloride, calcium chloride, magnesium chloride, or seawater; (b) clay, chosen to suit the saline concentration of the water and to provide the necessary properties; and (c) one or more viscosity increasing materials.
Claims15
A clay based aqueous drilling or completion mud comprising clay, density increasing material, viscosity increasing agent, and from 1 to 10 grams per liter of a hydrosoluble polymeric material having pendant groups and a weight average molecular weight not higher than about 40,000, wherein from about 2 to 95% of the pendant groups are independently hydroxamic or thiohydroxamic groups of the formula:
- ##STR7## wherein X.sub.1 and X.sub.2 are independently oxygen, or sulfur and R and R' are independently hydrogen, alkyl or cycloalkyl having from 1 to about 18 carbon atoms, alkylene and cycloalkylene having from about 2 to 18 carbon atoms, aryl, alkylaryl, arylalkyl, alkoxyaryl, and alkoxyalkyl, having up to two conjugated rings, and having up to about 18 carbon atoms and wherein said polymeric material before the introduction of the hydroxamic or thiohydroxamic groups, is a homopolymer of acrylamide, methacrylamide, alkylacrylamide, thioacrylamide, alkylthioacrylamide, and hydroxyalkylacrylates, or copolymers of a monomer selected from acrylamide, methacrylamide, alklyacrylamide, thioacrylamide, alkylthioacrylamide, and hydroxyalkylacrylates and a monomer selected from acrylic acid, alkylacrylic acid, salts of acrylic acid and alkylacrylic acid, esters of acrylic acid and alkylacrylic acid, maleicanhydride, vinylacetate, vinyl pyrrolidone, butadiene, styrene and acrylonitrile.
Dependencies are inferred from the claim text.