Large pore catalysts for heavy hydrocarbon conversion
AssigneeAshland Oil, Inc.
InventorsWilliam P. Hettinger, Jr., James E. Lewis
Life of this patent
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Abstract
Disclosed is a catalyst, a method for its preparation, and a process for its use in the production of high octane gasoline and/or other valuable liquid hydrocarbon products from carbo-metallic oils contaminated with heavy metals and coke precursors. The catalyst is prepared from a shapable composition containing reticulated carbon black particles which are subsequently removed by burning, as in a catalyst regenerator, to provide large feeder pores in a shaped catalyst structure. The catalyst and process conditions for its use facilitate conversion of the contaminated oils to lighter products at catalytic sites within the catalyst structure which may contain zeolitic materials.
Claims5
A process for the catalytic conversion of a hydrocarbon feedstock containing at least ten percent heavy hydrocarbon components boiling above 1025.degree. F., said process comprising contacting said feedstock with a catalyst,
- wherein said catalyst is characterized by an increased percentage of feeder pores having an average diameter in the size range of about 100 to 6000 .ANG. which results from admixing carbon black composed of primary reticulated particles having a length of about 500 to 30,000 .ANG., a carbon black dispersant and a shapeable catalyst composition having hydrocarbon conversion characteristics, wherein during said admixing controlling the agglomeration of the primary reticulated carbon black particles by the amount and dispersing effectiveness of said dispersant, to provide increased percentages of feeder pores in the range of about 100 to 6,000 .ANG., shaping said catalyst composition into solid shapes of hydrocarbon conversion catalyst containing 1 to 35 weight percent of said carbon black, and heating said catalyst shapes in the presence of an oxygen-containing gas at combustion conditions sufficient to remove said carbon black particles and provide large feeder pores of 100 to 6,000 .ANG. in said solid catalyst, in a reaction zone maintained under hydrocarbon conversion conditions providing hydrocarbon conversion products and depositing coke on said catalyst, stripping said hydrocarbon conversion products from said catalyst, regenerating said catalyst under oxidizing conditions sufficient to remove at least a portion of said deposit of coke from said catalyst, and returning said regenerated catalyst to said reaction zone.
Dependencies are inferred from the claim text.