A method for forming a powder dressing for wounds which consists of the sequence of steps of water swelling a mass of regenerated cellulose beads, contacting said water swollen beads with one of an organic solvent solution selected from the group consisting of (a) a water miscible, (b) a partly water miscible, or (c) a mixture of a water miscible and a water immisible organic solvent, and capable of absorbing at least 5% water to form a mixture of solvent and water, removing the water from said mixture until all the water in said mixture and said beads is replaced with solvent and said solvent maintains said beads swollen, removing said solvent and drying said beads, and separating from said dried beads those particles having a diameter of at least 0.05 mm and a macroporous structure characterized by a porosity in the dry state corresponding to the cyclohexane regain of at least 0.2 ml/g of the dry material.