Extrudable polyurethane for prosthetic devices prepared from a diisocyanate, a polytetramethylene ether polyol, and 1,4-butane diol
AssigneeThermedics Inc.
InventorMichael Szycher
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Abstract
Reaction product of an aliphatic organic diisocyanate, a high molecular weight polyether polyol (poly tetra methylene ether glycol) and 1,4 butane diol. The resulting polymers have thromboresistant properties, a long flexural life and are extrudable. The polyurethane polymer is ideal for forming transvenous cardiac pacemaker leads, blood bags, intravenous and intra-arterial catheters and tubing, and other shaped devices which must be formed of a blood compatible material.
Claims4
A polymer for use in extruding and molding devices requiring a high degree of blood compatibility, said polymer consisting essentially of a polyurethane elastomer which is the reaction product of:
- (a) dicyclohexyl methane diisocyanate;
- (b) a polytetramethylene ether polyol having a molecular weight in the range of 1000-3000;
- and
- (c) 1,4 butane diol,
- wherein the number of moles of dicylohexyl methane diisocyanate molecules is equal to the sum of the number of moles of polytetramethylene ether polyol and the number of moles of 1,4 butane diol;
- the molar ratio of 1,4 butane diol to polytetramethylene ether glycol is between 1.1 to 0.9 and 1.5 to 0.5;
- and
- the average molecular weight of the polymer is 120,000-180,000 units, and a weight average molecular weight of 285,000-335,000 molecular weight units.
Dependencies are inferred from the claim text.