# US 4,521,332 A · Highly alkaline cleaning dispersion

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- Number: US 4,521,332 A
- Document ID: US4521332A
- Status: Granted
- Kind: A
- Application number: 06/373,924
- Filed: 1982-05-03
- Granted: 1985-06-04
- Earliest claimed: 1980-05-27
- Assignees: Pennwalt Corporation
- Inventors: David J. Milora
- Web page: https://patentgrep.com/patent/US4521332A

## CPC

- C23G 1/19: Iron or steel
- C11D 3/3765: {in liquid compositions}
- C11D 7/06: Hydroxides
- C23G: CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C11D: DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL

## Abstract

A highly alkaline aqueous cleaning dispersion comprising sodium hydroxide, a bulking agent such as sodium carbonate and polyacrylic acid dispersing agent is disclosed and claimed. The dispersion when diluted with water is particularly useful in cleaning strip steel after it leaves the rolling mills prior to annealing or coating. A method of preparing the dispersion is also claimed.

## Claims

### Claim 1

A liquid highly alkaline aqueous cleaning dispersion which resists separation into layers said dispersion containing at least about 40% solids by weight and comprising the following ingredients expressed as percent by weight:
Sodium hydroxide: 10 to 45%
Alkali metal or ammonium salt of polyacrylic acid having a molecular weight within the range of 500 to 12,000: 0.04% to gelling
Alkali metal phosphate builder: 2 to 15%
Nonionic surfactant: 0.3 to 5%
Chelator: 0.25 to 3%
Sodium or potassium carbonate as a bulking agent: 0.5 to 20%
Water: Balance
in which the chelator is one or more members selected from group consisting of sorbitol, gluconic acid, glucoheptonic acid, mannitol, ascorbic acid, sorbose, tannic acid, ethylenediamine tetraacetic acid, sodium chrom glucosate, diglycolic acid, aspartic acid, d-gluconolactone, l-rhamnose, nitrilotriacetic acid, and the sodium or potassium salts of the acids.

### Claim 2 (depends on 1)

The cleaning dispersion of claim 1 in which the alkali metal or ammonium salt of polyacrylic acid is present at a concentration of 0.04 to 4% by weight.

### Claim 3 (depends on 1)

The cleaning dispersion of claim 1 in which the alkali metal phosphate builder is one or more members selected from the group consisting of sodium hexametaphosphate, sodium tripolyphosphate, tetrapotassium pyrophosphate, tetrasodium pyrophosphate, trisodium phosphate, disodium phosphate, monosodium phosphate, monopotassium phosphate, dipotassium phosphate and tripotassium phosphate.

### Claim 4 (depends on 1)

The cleaning dispersion of claim 1 in which the alkali metal phosphate builder is sodium hexametaphosphate and the chelator is sodium gluconate.

### Claim 5 (depends on 1)

The cleaning dispersion of claim 1 in which the bulking agent is sodium carbonate.

### Claim 6 (depends on 1)

The cleaning composition of claim 1 wherein the nonionic surfactant is selected from the group consisting of linear and branch chain ethoxylated alcohols and ethoxylated alkyl and dialkyl phenols.

### Claim 7

A liquid highly alkaline aqueous cleaning dispersion which resists separation into layers comprising the following ingredients expressed as percent by weight:
Sodium hydroxide aqueous solution (50% NaOH): 84.25%
Sodium salt of polyacrylic acid having a molecular weight within the range of 500 to 12,000 (40% conc.): 1.0%
Sodium hexametaphosphate: 2.0%
Nonionic surfactant: 1.0%
Sodium gluconate: 0.5%
Tetrasodium ethylenediamine tetraacetic acid: 0.25%
Sodium carbonate: 2.0%
Water: 9.0%.

### Claim 8

A liquid highly alkaline aqueous cleaning dispersion which resists separation into layers comprising the following ingredients expressed as percent by weight:
Sodium hydroxide aqueous solution (50% NaOH): 21.0%
Sodium hexametaphosphate: 10.0%
Sodium gluconate: 0.50%
Tetrasodium ethylenediamine tetraacetic acid: 0.25%
Sodium salt of polyacrylic acid having a molecular weight within the range of 500 to 12,000: 1.0%
Sodium carbonate: 20.0%
Water: 47.25%.