Electroactive polymers
AssigneeChevron Research Company
InventorYoram S. Papir
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Abstract
Tractable doped electroactive polymers, comprising recurring units of a fused nitrogen-containing unsaturated heterocyclic ring system, are fabricated from the virgin polymer by contacting the polymer with donor or acceptor conductivity modifier atoms or groups of atoms.
Claims42
A tractable electroactive polymer which comprises a charged polymer backbone of recurring units of a fused 6,6-membered nitrogen-containing unsaturated heterocyclic ring system and charge compensating ionic dopant associated therewith, wherein the polymer backbone is capable of undergoing a reversible oxidation or a reversible reduction or both to form said charged polymer backbone.
A tractable electroactive polymer which comprises a charged polymer backbone and charge compensating ionic dopants associated therewith of the formula ##STR39## wherein a is 0 or 1;
- b is 0 or 1;
- c is 0 or 1;
- n is an integer from 2 to 20,000;
- d is an integer from 1 to 40,000;
- S is an integer 1, 2, or 3;
- R is a fused 6,6-membered nitrogen-containing unsaturated diradical-heterocyclic ring system;
- R' is the same as R or a different fused 6,6-membered unsaturated heterocyclic ring system;
- X is a connecting unit;
- Y is the same connecting unit as X or a different connecting unit;
- and M is a charge compensating ionic dopant of opposite electrical charge to the charge of the polymer backbone, wherein the polymer backbone is capable of undergoing reversible oxidation or a reversible reduction or both to form said charged polymer backbone and wherein said X or Y connecting unit is an atom or group of atoms which can link the R or R' diradicals into said polymer backbone, said connecting unit is selected from the group consisting of ##STR40## wherein R.sup.v, R.sup.vi and R.sup.vii are H or methyl, and mixtures of said connecting units.
A polymer which comprises recurring units of the formula:
- ##STR56## wherein R is alkoxy C.sub.1 -C.sub.4 or a halogen.
Dependencies are inferred from the claim text.