Helichromic-smectic liquid crystal compositions and display cells
AssigneeMinnesota Mining and Manufacturing Company
InventorsWilliam A. Huffman, Harvey A. Brown
Life of this patent
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Abstract
A composition for use in thermally-addressable liquid crystal display devices, comprising a smectic liquid crystal material and a helichromic compound possessing both a chromophoric moiety and an optically-active moiety. The helichromic compound is a circularly dichroic dye capable of propagating incident visible light in a circularly polarized manner so that all polarizations of the incident light are absorbed. The composition comprising the helichromic compound can be utilized in thermally-addressable liquid crystal display devices to provide a display which operates at lower voltages, with faster response times, and higher contrast ratios.
Claims26
A composition consisting essentially of a smectic liquid crystal material, and, in admixture therewith, an organic, nonionic, nonliquid-crystalline helichromic compound, said helichromic compound being soluble in said smectic liquid crystal material, said helichromic compound being a circularly dichroic dye, and said helichromic compound having the general formula
- Q--Z).sub.n
- wherein
- Q is an organic group having a chromophoric character;
- Z is an optically-active organic group;
- and n is an integer having a value of 1 or greater.
A thermally addressable liquid crystal display device having no auxiliary polarizers, which provides a high contrast image against a background comprising:
- a layer of a composition consisting essentially of a liquid crystal medium in admixture with an organic, nonionic, nonliquid-crystalline helichromic compound, said layer disposed between a top substrate and a bottom substrate, said helichromic compound being soluble in said liquid crystal medium, said helichromic compound being a circularly dichroic dye, and said helichromic compound having the general formula
- Q(Z).sub.n
- wherein
- Q is an organic group having a chromophoric character;
- Z is an optically-active organic group;
- and
- n is an integer having a value of 1 or greater;
- said liquid crystal medium being thermally sensitive and having a transition between at least two thermal phases, an upper phase being a nematic phase and a lower thermal phase being a smectic phase, said mixture having two possible states of orientation in said smectic phase, a first orientation state being substantially light absorbing and a second state being substantially light transmissive;
- a means of affecting a thermal transition between said lower thermal phase and said upper thermal phase;
- and
- a means of electrically addressing portions of said mixture to develop said second light transmissive state when said mixture passes rapidly into said lower thermal state from said upper thermal state, the remaining unaddressed portions of said mixture developing said first substantially light absorbing state when said mixture passes rapidly into said lower thermal state from said upper thermal state.
Dependencies are inferred from the claim text.