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US 4,513,132 AGranted
Heat-resistant silicone block polymer
AssigneeHitachi, Ltd.
InventorsFusaji Shoji, Issei Takemoto, Fumio Kataoka, Hitoshi Yokono, Tokio Isogai
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Abstract
Heat-resistant silicone block polymer with a good flexibility obtained by reaction of an organosilsesquioxane with a silicone compound or organosiloxane in the presence of a basic catalyst in an organic solvent.
Claims7
A heat-resistant silicone block polymer obtained by reaction of 100 parts by weight of organosilsesquioxane having the following formula (5):
- ##STR17## wherein R.sup.1 is a lower alkyl group having 1 to 5 carbon atoms and/or an aryl group and n is an integer of from 0 to 4,000, with 5 to 400 parts by weight of a silicone compound or organosiloxane represented by the formula (6) or (7):
- ##STR18## wherein R.sup.2 is an arylene group, R.sup.3 and R.sup.4 are lower alkyl groups having 1 to 5 carbon atoms, alkenyl groups and/or aryl groups, and X is a chlorine atom, a hydroxyl group, an alkoxy group or an N,N-dialkylamino group, or ##STR19## wherein R.sup.2, R.sup.3 and R.sup.4 and X have the same meanings as defined heretofore and p is an integer of from 0 to 100, in an organic solvent and in the presence of 0.1 to 200 parts by weight of a basic catalyst per 100 parts by weight of the compound of the general formula (5).
Dependencies are inferred from the claim text.