A process for the preparation of finely dispersed, easily spreadable, aqueous polyurethane reactive coating compositions suitable for coating textile sheet products, artificial leather or leather by the direct or transfer coating process, which comprises
- (i) forming an aqueous dispersion having a solids content of about 20-69 wt. % of
- (a) blocked isocyanate prepolymers in the presence of
- (b) from about 0.05-5% by weight, based on (a), of emulsifiers,
- (ii) adding before, during or after formation of the dispersion
- (c) optionally levelling agents, pigments, fillers or stabilizers and
- (d) about 0.1 to 2.5% by weight, based on (a), of water soluble thickeners based on long chain polyethylene oxides, salts of poly(meth)acrylic acids or salts of carboxy methyl cellulose,
- (iii) adding after formation of the dispersion
- (e) up to 100% by weight of polymer solid substance, based on (a) of aqueous polymer solutions and/or polymer dispersions, and
- (iv) forming said coating composition having a viscosity of from about 3000 to 22,000 mPa.s/25.degree. C. and with a solids content of about 20-69% by weight, by adding before, during or after formation of the dispersion,
- (f) approximately equivalent quantities, based on the blocked isocyanate groups of (a), of (cyclo)aliphatic di- and/or polyamines.