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US 4,503,018 AGranted
Desulfurization of phosphogypsum
AssigneeDavy McKee Aktiengesellschaft
InventorsSamuel A. Gardner, Thomas E. Ban
Life of this patent
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Abstract
Phosphogypsum is mixed with fine coal, balled, and charged to a travelling grate where the charge is heated under reducing conditions to evolve sulfur and/or sulfur dioxide for conversion into sulfuric acid.
Claims14
A process for producing sulfur and/or sulfur dioxide from gypsum comprising the steps of:
- forming a mixture of fine carbon material and fine gypsum material,
- balling the mixture to form pellets,
- charging the pellets to a travelling grate,
- moving the travelling grate to carry the charge of pellets successively through firing and post firing zones,
- heating the charge on the grate in the firing zone under non-oxidizing conditions to produce a gaseous effluent containing sulfur dioxide or sulfur or both sulfur and sulfur dioxide, and
- passing a portion of the gaseous effluent from the firing zone through the charge in the post firing zone.
3 more elements
A process for producing sulfur and/or sulfur dioxide from phosphogypsum comprising the steps of
- forming a mixture of fine high-sulfur content coal and fine phosphogypsum so that the mixture includes at least about 3 to 8 parts by weight fixed carbon content for every 92 to 97 parts by weight gypsum content,
- balling the mixture to form pellets having a diameter of about 13 mm,
- charging the pellets to a circular travelling grate to form a layer of pellets on the grate,
- moving the grate and layer of pellets successively through drying, firing, post firing and cooling zones in a sealed hood arrangement,
- burning high sulfur content fuel in a fixed bed gas producer to produce a hot raw low BTU gas,
- feeding the hot gas to the firing zone to heat the pellets to about 1200.degree. C. to produce a product gas containing sulfur or sulfur dioxide or both sulfur and sulfur dioxide from the pellets,
- removing the product gas from the firing zone, and
- passing a portion of the product gas through the charge in the post firing zone.
5 more elements
Dependencies are inferred from the claim text.