Adherent controlled release microbiocides containing hydrolyzable silanes and organic titanium compounds

A composition capable of undergoing hydrolysis under ambient conditions to form a polymeric network capable of controlling the release of a microbiocide, consisting essentially of (a) a hydrolyzable silane selected from the group consisting of (1) a hydrocarbon substituted hydrolyzable silane, and (2) an organopolysiloxane containing hydrolyzable silane groups, or a partial hydrolyzate thereof, (b) a hydrolyzable titanium compound or a partial hydrolyzate thereof, said titanium compound being selected from the group consisting of (1) tetraesters, tetraanhydrides and tetraamides, and (2) chelates of glycols, hydroxy acids, dicarboxylic acids, diketones, ketoesters and alkanolamines, (c) a hydroxyl-containing polymer selected from the group consisting of (1) an organopolysiloxane containing hydroxyl groups or functional groups which are hydrolyzable to hydroxyl groups, and (2) a carbinol-containing polymer, and (d) a microbiocide.

A composition capable of undergoing hydrolysis under ambient conditions to form a polymeric network capable of controlling the release of a microbiocide, consisting essentially of (a) a hydrolyzable silane selected from the group consisting of (1) a hydrocarbon substituted hydrolyzable silane, and (2) an organopolysiloxane containing hydrolyzable silane groups, or a partial hydrolyzate thereof, (b) a hydrolyzable titanium compound or a partial hydrolyzate thereof, said titanium compound being selected from the group consisting of (1) tetraesters, tetraanhydrides and tetraamides, and (2) chelates of glycols, hydroxy acids, dicarboxylic acids, diketones, ketoesters and alkanolamines, (c) a hydroxyl-containing polymer selected from the group consisting of (1) an organopolysiloxane containing hydroxyl groups or functional groups which are hydrolyzable to hydroxyl groups, and (2) a carbinol-containing polymer, (d) a non-volatile, non-reactive extender, and (e) a microbiocide, wherein the weight ratio of (a+b)/c is within the range 0.1/99.9 to 100/0 and the weight ratio of (a) and (b) is within the range 0.1/99.9 to 99.9/0.1.

A composition capable of undergoing hydrolysis under ambient conditions to form a polymeric network capable of controlling the release of a microbiocide, consisting essentially of (a) a hydrolyzable silane selected from the group consisting of (1) a hydrocarbon substituted hydrolyzable silane, and (2) an organopolysiloxane containing hydrolyzable silane groups, or a partial hydrolyzate thereof, (b) a hydrolyzable titanium compound or a partial hydrolyzate thereof, said titanium compound being selected from the group consisting of (1) tetraesters, tetraanhydrides and tetraamides, and (2) chelates of glycols, hydroxy acids, dicarboxylic acids, diketones, ketoesters and alkanolamines, (c) a hydroxyl-containing polymer selected from the group consisting of (1) an organopolysiloxane containing hydroxyl groups or functional groups which are hydrolyzable to hydroxyl groups, and (2) a carbinol-containing polymer, (d) a volatile diluent, and (e) a microbiocide, wherein the weight ratio of (a+b)/c is within the range 0.1/99.9 to 100/0 and the weight ratio of (a) and (b) is within the range 0.1/99.9 to 99.9/0.1.

A composition capable of undergoing hydrolysis under ambient conditions to form a polymeric network capable of controlling the release of a microbiocide, consisting essentially of (a) a hydrolyzable silane selected from the group consisting of (1) a hydrocarbon substituted hydrolyzable silane, and (2) an organopolysiloxane containing hydrolyzable silane groups, or a partial hydrolyzate thereof, (b) a hydrolyzable titanium compound or a partial hydrolyzate thereof, said titanium compound being selected from the group consisting of (1) tetraesters, tetraanhydrides and tetraamides, and (2) chelates of glycols, hydroxy acids, dicarboxylic acids, diketones, ketoesters and alkanolamines, (c) a hydroxyl-containing polymer selected from the group consisting of (1) an organopolysiloxane containing hydroxyl groups or functional groups which are hydrolyzable to hydroxyl groups, and (2) a carbinol-containing polymer, (d) a non-volatile, non-reactive extender, (e) a volatile diluent, and (f) a microbiocide, wherein the weight ratio of (a+b)/c is within the range 0.1/99.9 to 100/0 and the weight ratio of (a) and (b) is within the range 0.1/99.9 to 99.9/0.1.