Hydrotreatment for petroleum cuts with offretite
AssigneeElf France
InventorsJacques Bousquet, Claude Guguen
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AssigneeElf France
InventorsJacques Bousquet, Claude Guguen
Estimating the term…
The present invention concerns a hydrotreatment process for petroleum cuts, in order to achieve simultaneously their desulfurization and the improvement of their flow properties. The process comprises treating the cuts in the presence of a catalytic system based on a zeolitic crystalline silico aluminate of the offretite type, wherein the synthetic offretite used has a crystalline structure identical to natural offretite and has the chemical formula (M.sub.1 M.sub.2 . . . ).sub.2 (Al.sub.2 O.sub.3) (SiO.sub.2).sub.y in which y is comprised between 10 and 50, M.sub.1 and M.sub.2 are selected from among cations of group I and II of the Periodic Table of Elements and this offretite is associated with a bimetallic catalyst comprising a mixture of an oxide or sulfide of a metal selected from among the group comprising chromium, molybdenum and tungsten with an oxide or a sulfide of a metal selected from among the group comprising iron, cobalt and nickel.
A hydrotreatment process for petroleum cuts containing sulfur for simultaneous desulfurization and improvement of flow properties by conversion of n-paraffins, comprising contacting the sulfur containing cuts at a temperature of 200.degree. to 500.degree. C., a pressure of 1 to 80 bars, a liquid spatial velocity of the load (LSV) of 0.3 to 6 m.sup.3 /m.sup.3 /h, with hydrogen at a hydrogen/hydrocarbon molar ratio between 2 and 10, in the presence of a catalytic system based on a synthetic zeolitic crystalline silico aluminate of the offretite structure having the chemical formula (M.sub.1,M.sub.2 . . . ).sub.2 (Al.sub.2 O.sub.3)(Sio.sub.2).sub.y wherein y is between 10 and 50, M.sub.1 and M.sub.2 are selected from cations of the groups I and II of the Periodic Table of Elements, the offretite is impregnated with a mixture of oxides or sulfides of at least one metal selected from the group consisting of chromium, molybdenum and tungsten with an oxide or a sulfide of at least one metal selected from the group consisting of iron, cobalt and nickel.
Dependencies are inferred from the claim text.