Self-crosslinking heat-curable binder
AssigneeBASF Farben & Fasern AG
InventorsMichael Geist, Horst Diefenbach
Life of this patent
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Abstract
The invention relates to a self-crosslinking heatcurable binder, in particular for electropaints, which is based on an organic synthetic resin which contains primary and/or secondary and, if desired, also tertiary amino groups and esterified carboxyl groups and is water-dilutable due to partial or complete neutralization with acids. The esterified carboxyl groups are activated in the alcohol component by a substituent which induces a negative inductive effect.
Claims9
A self-cross-linking heat-curable binder based on an organic synthetic resin which contains amino groups and esterified carboxyl groups and is water-dilutable due to neutralization with acids, in which the esterified carboxyl groups are activated in the alcohol component and are .beta.-hydroxylalkyl ester groups or carbalkoxymethyl ester groups and said organic synthetic resin is an epoxy resin which has been prepared by reacting a polyglycidyl ester or ether with a compound which carries two groups which are reactive toward epoxy groups and at least one of said esterified carboxyl groups to give an intermediate produce having terminal epoxy groups, and reacting said terminal epoxy groups having open rings with a compound selected from the group consisting of primary amines, secondary amines, ketimines having a hydrogen atom on the nitrogen atom, and aminoalcohols blocked at the nitrogen atom or a polyurethane resin which has been prepared by reacting a diisocyanate with a compound which carries two groups which are reactive toward isocyanate groups and at least one of said esterified carboxyl groups to give an intermediate product having terminal isocyanate groups, and reacting said terminal isocyanate groups with a compound selected from the group consisting of primary amines, secondary amines, ketimines having a hydrogen atom on the nitrogen atom, aldimines having a hydrogen atom on the nitrogen atom, and aminoalcohols blocked at the nitrogen atom.
A process for preparing a binder which comprises reacting polyglycidyl ester or polyglycidyl ether with a first compound which carries two groups which are reactive toward epoxy groups and at least one carboxylate group which is activated in the alcohol component and are .beta.-hydroxyalkyl ester groups or carbalkoxymethyl ester groups to give an intermediate product having terminal epoxy groups, and reacting these epoxy groups having open rings with a second compound selected from the group consisting of amines, secondary amines, ketimines having a hydrogen atom on the nitrogen atom, aldimines having a hydrogen atom on the nitrogen atom, and aminoalcohols blocked at the nitrogen atom.
A process for preparing a binder which comprises reacting a diisocyanate with a first compound which carries two groups which are reactive toward isocyanate groups and at least one carboxylate group which is activated in the alcohol component and are .beta.-hydroxyalkyl ester groups or carbalkoxy methyl ester groups to give an intermediate product having terminal isocyanate groups, and reacting these isocyanate groups with a second compound selected from the group consisting of primary amines, secondary amines, ketimines having a hydrogen atom on the nitrogen atom, aldimines having a hydrogen atom on the nitrogen atom, and aminoalcohols blocked at the nitrogen atom.
Dependencies are inferred from the claim text.