Semi-conductive compositions, based on ethylene-vinyl acetate copolymers, having adhesion to and strippability from crosslinked polyolefin substrates
AssigneeUnion Carbide Corporation
InventorsSeiho Taniguchi, Yuichiro Sakuma
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Abstract
Semi-conductive compositions, based on ethylene-vinyl acetate copolymers or chlorinated products thereof, containing carbon black, a silicone compound and an interface crosslink inhibitor, such as a phenol, a quinone, a thiazole or a thiuram sulfide, which find utility as semi-conductive layers about crosslinked polyolefin substrates of electrical conductors.
Claims15
A semi-conductive composition comprising an ethylene-vinyl acetate copolymer containing 15 to 30 percent by weight vinyl acetate and having a melt index of 1 to 50 g/10 min. or a chlorinated product thereof containing 3 to 40 percent by weight chlorine, carbon black, a silicone compound selected from the group consisting of silicone oils, silicone rubbers and silicone block copolymers which are liquid at normal temperatures, in an amount of about 0.3 to about 5 parts by weight and an interface crosslink inhibitor selected from the group consisting of a phenol, a quinone, a thiazole and a thiuram sulfide in an amount of about 0.01 to about 1.5 parts by weight, said parts by weight based on 100 parts by weight of said copolymer.
A semi-conductive composition comprising an ethylene-vinyl acetate copolymer containing 15 to 30 percent by weight vinyl acetate and having a melt index of 1 to 50 g/10 min. or a chlorinated product thereof containing 3 to 40 percent by weight chlorine, carbon black, a silicone compound selected from the group consisting of silicone oils, silicone rubbers and silicone block copolymers which are liquid at normal tempertures, in an amount of about 0.3 to about 5 parts by weight and an interface crosslink inhibitor, in an amount of about 0.01 to about 1.5 parts by weight, selected from the group consisting of 2,2'-methylene-bis-(4-methyl-6-t-butyl phenol), 2,6-di-t-butyl-4-methyl phenol, 4,4'-thio-bis(6-t-butyl-2-methyl phenol), t-butyl catechol, hydroquinone, 2,5-di-t-butyl hydroquinone, 2-mercapto benzothiazole, 2,2'-thio-bis-benzothiazole, N-cyclohexyl-benzothiazole-sulfeneamide and tetramethyl thiuram disulfide.
Dependencies are inferred from the claim text.