Preparation of ultrapure boehmites and/or pseudo-boehmites
AssigneeRhone-Poulenc Specialites Chimiques
InventorEmile Trebillon
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AssigneeRhone-Poulenc Specialites Chimiques
InventorEmile Trebillon
Estimating the term…
Ultrapure and homogeneous boehmites and/or pseudo-boehmites, suitable, whether before or after drying and/or calcination, as, e.g., fillers, binders, thickeners, dispersing agents, and the like, are prepared (i) by admixing an amorphous aluminum hydroxycarbonate, itself advantageously prepared by carbonating an alkali metal aluminate with carbon dioxide and then filtering and washing the precipitate which results, with a solution of an acid, a base, a salt, or mixture thereof, with the pH of the resulting reaction medium being maintained at a value of less than 11, (ii) next heating such reaction medium at a temperature of less than 90.degree. C. for a period of at least 5 minutes, and (iii) then heating the reaction medium resulting from the step (ii) at a temperature ranging from 90.degree. C. to 250.degree. C.
A process for the preparation of ultrapure and homogeneous boehmite and pseudo-boehmite, comprising (i) admixing amorphous aluminum hydroxycarbonate which has been prepared by carbonating an alkali metal aluminate with carbon dioxide and then filtering and washing the precipitate which results, with a solution of an acid, a base, a salt, or mixture thereof, with the pH of the reaction medium which results being maintained at a value of less than 11, (ii) next heating such reaction medium at a temperature of less than 90.degree. C. for a period of at least 5 minutes, and (iii) thence heating the reacting medium resulting from the step (ii) at a temperature ranging from 90.degree. C. to 250.degree. C.
A process for the preparation of ultrapure and homogeneous boehmite and pseudo-boehmite, comprising (i) admixing amorphous aluminum hydroxycarbonate with a solution of an acid, a base, a salt, or mixture thereof, with the pH of the reaction medium which results being maintained at a value of less than 11, wherein the amorphous aluminum hydroxycarbonate is prepared by carbonating an alkali metal aluminate with carbon dioxide at a temperature ranging from 0.degree. C. to 60.degree. C. for less than 30 minutes and with the pH of the carbonation reaction medium ranging from 7 to 11.5, and thence filtering and washing the precipitate which results with water until the wash waters have a resistivity in excess of 10.sup.5 .OMEGA.. cm, measured at 20.degree. C., and wherein the molar ratio of the sum of the anions and cations in the mixture, other than H.sup.+ and OH.sup.-, to the equivalent of the aluminum compound, expressed as Al.sub.2 O.sub.3, ranges from 0.01 to 2, (ii) next heating the resulting reaction medium at a temperature of less than 90.degree. C. for a period of at least 5 minutes, and (iii) thence heating the reaction medium resulting from the step (ii) at a temperature ranging from 90.degree. C. to 250.degree. C.
Dependencies are inferred from the claim text.