US 4,482,775 AGranted

Isomerization of C.sub.4 alkenes

AssigneeChemical Research & Licensing Company

InventorLawrence A. Smith, Jr.

Life of this patent

Estimating the term…

Loading patent…

Abstract

A method for isomerizing isobutene or n-butene to produce a mixture of isobutene and normal butene, and polymerizing at least a portion thereof to produce isobutene/n-butene codimer, which comprieses feeding at least 80 weight % of either the isobutene or n-butene to a catalytic distillation reactor containing a fixed bed acidic cation exchange resin catalyst packing which provides both the catalyst sites and distillation sites for the reaction products, isomerizing a portion of the isobutene or n-butene to produce a mixture of isobutene and n-butene and reacting at least a portion of the isobutene and n-butene to form codimer of isobutene and n-butene, whereby an overhead fraction containing any unreacted isobutene and n-butene and a bottoms fraction containing codimer is produced. The result of the reaction is substantially the same regardless whether the feed is isobutene or n-butene. Other aspects of the invention, include combinations of procedures to produce high purity isobutene and n-butene. Either isobutene or n-butene product (depending on the desired product) can be recycled as feed, thus substantially carrying out the isomerization to extinction and total conversion to the desired product.

Claims6

Dependent claims

A method for producing high purity isobutene comprising:

(a) feeding a hydrocarbon stream wherein the predominant reactive hydrocarbon comprises at least 80 weight percent n-butene to a distillation column reactor containing a fixed bed acidic cation exchange resin packing,
(b) concurrently in said distillation column reactor:
(1) contacting said n-butene with said fixed bed to isomerize a portion thereof to form a mixture of isobutene and n-butene,
(2) reacting a portion of said normal butene with a portion of said isobutene to form codimer, and
(3) fractionating the resulting mixture at a reflux ratio of 0.5 to 20:1,
(c) withdrawing an overhead containing isobutene and n-butene at a point above said fixed bed,
(d) withdrawing said codimer at a point below said fixed bed,
(e) depolymerizing said codimer to produce an isobutene and n-butene stream,
(f) contacting said depolymerized stream with an acidic cation exchange resin and an alcohol to selectively react said isobutene with said alcohol to form an ether,
(g) separating said ether and unreacted n-butene by fractionation,
(h) recovering an n-butene overhead,
(i) recovering an ether bottoms product,
(j) contacting said ether product in vapor phase with an acidic catalyst to dissociate said ether into isobutene and alcohol,
(k) separating said alcohol and said isobutene and
(l) recovering said isobutene.

12 more elements

Dependencies are inferred from the claim text.

Facts

Application: 06/421,588Filed 22 Sep 1982
Granted: 13 Nov 1984
Term ends: Not estimatedThe source records don’t support an estimate.

Classification11 codes

C07C 7/005
Purification; Separation; Use of additives: processes comprising at least two steps in series
B01D 3/009
Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping: in combination with chemical reactions
C07C 7/148
Purification; Separation; Use of additives: by treatment giving rise to a chemical modification of at least one compound
Y02P 20/10
Technologies relating to chemical industry: process efficiency