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US 4,477,629 AGranted
Cyanate-containing polymers
AssigneeThe Dow Chemical Company
InventorRobert E. Hefner, Jr.
Life of this patent
Estimating the term…
Abstract
New compositions of matter are disclosed which comprise (1) a cyanate-containing polymer or mixture thereof and optionally (2) a polycyanate or mixture thereof and/or (3) an epoxy resin. These compositions are thermosettable upon heating in the presence of suitable curing agents or catalysts.
Claims8
A composition which comprises
- (A) from about 1 to 100 percent by weight (pbw) of a cyanate-containing polymer or mixture of cyanate-containing polymers represented by the formula:
- ##STR7## wherein each R, R' and R" is independently hydrogen or an alkyl group having from 1 to about 4 carbon atoms;
- each X is independently an alkyl group having from 1 to about 4 carbon atoms, chlorine or bromine;
- Q is independently a group derived from any suitable polymerization initiator or terminator, ##STR8## wherein each aromatic ring may contain any substituent group as those enumerated in formula I and each R, R' and R" is defined as in formula I;
- n has a value from about 5 to about 100;
- n' has a value from zero to about 99;
- and each x independently has a value from zero to 4;
- and
- (B) from zero to about 99 pbw of an aromatic polycyanate or mixture of aromatic polycyanates represented by the formula:
- ##STR9## wherein each Z is independently H-, an alkyl group having from 1 to about 4 carbon atoms, chlorine or bromine;
- A is a direct bond, a hydrocarbyl group having from 1 to about 10 carbon atoms, --S--, --S--S--, --O--, ##STR10## y has a value from zero to 5 when n" has a value of 1;
- y has a value from 2 to 5 when n" has a value of zero;
- x' has a value of 5 minus the value of y when n" has a value of 1;
- x' has a value of 6 minus the values of y plus y" when n" has a value of zero;
- x" has a value of 5 minus the value of y";
- y" has a value of zero to 5;
- n" has a value of zero to 3;
- with the proviso that the sum of y and y" is always at least two;
- and
- (C) from zero to about 99 pbw of an epoxy resin or mixture of epoxy resins represented by the formulas:
- ##STR11## wherein R, X, Z, n', and x are as defined above;
- m' has a value of 0.01 to about 10, and each A is independently a hydrocarbyl group having from 1 to about 10 carbon atoms, --S--, --S--S--, --O--, ##STR12## each A' is independently a hydrocarbyl group having from 1 to about 10 carbon atoms;
- each m has a value of zero or 1;
- wherein the pbw of the individual components is based upon the total weight of components A, B and C.
21 more elements
Dependencies are inferred from the claim text.