Process for the preparation of thiuram disulfides
AssigneeAkzona Incorporated
InventorsLudwig Eisenhuth, Hans G. Zengel, Manfred Bergfeld
Life of this patent
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Abstract
A process for the preparation of thiuram disulfides substituted with aliphatic, cycloaliphatic, araliphatic, or aromatic hydrocarbon radicals, said process comprising reacting a suitably substituted secondary amine with carbon disulfide and in the presence of a tertiary amine or ammonia, oxygen or oxygen-containing gas, a solvent, and a metalliferous catalyst, at a temperature of between 0.degree. C. and 200.degree. C.
Claims9
A process for the preparation of thiuram disulfides substituted with aliphatic, araliphatic, or aromatic hydrocarbon radicals, said process comprising reacting a suitably substituted secondary amine with carbon disulfide in a solvent in the presence of a tertiary amine or ammonia, oxygen or an oxygen-containing gas, and metalliferous catalyst, wherein said carbon disulfide and said secondary amine are reacted in a molar ratio of 1.0 to 1.2:1, said reaction being maintained at a temperature between 0.degree. and 200.degree. C., said metalliferous catalyst being selected from the group consisting of elemental copper, copper(I) chloride, copper(I) bromide, copper(I) iodide, addition compounds of copper(I) halides with carbon monoxide, alkali chlorocuprates, complex ammoniacates of copper(I) cyanide, potassium tricyanocuprate(I), double salts with copper(I) thiocyanate, copper(I) acetate, copper(I) sulfide, complex double sulfides of copper(I) sulfide, alkali polysulfides, copper(II) chloride, copper(III) bromide, copper(II) sulfide, copper(II) nitrate, copper(II) thiocyanate, copper(II) cyanide, copper(II) acetate, copper dithiocarbamate, complex ammoniacates of copper(II) salts, copper(I) oxide, metallic cerium, cerium dioxide, cerium(III) chloride, cerium chloride, cerium chlorocomplex salts, cerium nitrate, cerium nitrato salts, cerium sulfate, cerium carbonate, cerium oxalate, cerium sulfides, vanadium oxide, vanadium chloride, vanadium sulfates, molybdenum oxides, molybdenum chloride, molybdenum sulfide, molybdenum fluoride, molybdates, molybdenum complex acido salts, powdered manganese, manganese dioxide, potassium permanganates, manganese dithiocarbamates, manganese acetate, the manganese derivatives corresponding to the above copper compounds, iron oxides, iron(II) and iron(III) salts, complex iron salts, cobalt oxides, cobalt(II) salts, cobalt complex salts, and double and complex vanadium salts.
A process for the preparation of thiuram disulfides substituted with aliphatic, cycloaliphatic, araliphatic and or aromatic hydrocarbon radicals, said process comprising reacting carbon disulfide, a suitably substituted secondary amine, and a tertiary amine or ammonia in equlmolar quantities to form a mixture, and reacting said mixture with carbon disulfide in the presence of oxygen or a gas containing oxygen, a solvent, and a metalliferous catalyst, said reaction being maintained at a temperature between 0.degree. C. and 200.degree. C., said metalliferous catalyst being selected from the group consisting of elemental copper, copper(I) chloride, copper(I) bromide, copper(I) iodide, addition compounds of copper(I) halides with carbon monoxide, alkali chlorocuprates, addition compounds of copper(I) halides with carbon monoxide, alkali chlorocuprates, complex ammoniacates of copper(I) cyanide, potassium tricyanocuprate(I), double salts with copper(I) thiocyanate, copper(I) acetate, copper(I) sulfide, complex double sulfides of copper(I) sulfide, alkali polysulfides, copper(II) chloride, copper(II) bromide, copper(II) sulfide, copper(II) nitrite, copper(II) thiocyanate, copper(II) cyanide, copper(II) acetate, copper dithiocarbamate, complex ammoniacates of copper(II) salts, copper(I) oxide, metallic cerium, cerium dioxide, cerium(III) chloride, cerium chloride, cerium chlorocomplex salts, cerium nitrate, cerium nitrato salts, cerium sulfate, cerium carbonate, cerium oxalate, cerium sulfides, vanadium oxide, vanadium chloride, vanadium sulfates, molybdenum oxides, molybdenum chloride, molybdenum sulfide and molybdenum fluoride, molybdates, molybdenum complex acido salts, powered manganese, manganese dioxide, potassium permanganates, manganese dithiocarbamates, manganese acetate, the manganese derivatives corresponding to the above copper compounds, iron oxides, iron(II) and iron(III) salts, complex iron salts, cobalt oxides, cobalt(II) salts, cobalt complex salts, and double and complex vanadium salts.
A process for the preparation of thiuram disulfides substituted with aliphatic, cycloaliphatic, araliphatic, or aromatic hydrocarbon radicals, said process comprising reacting carbon disulfide, a suitably substituted secondary amine and a tertiary amine or ammonia to form a dithiocarbamate, and reacting said dithiocarbamate in the presence of a metalliferous catalyst, a solvent, and oxygen or an oxygen-containing gas, said process being maintained at a reaction temperature between 0.degree. C. and 200.degree. C., said metalliferous catalyst being selected from the group consisting of elemental copper, copper(I) chloride, copper(I) bromide, copper(I) iodide, addition compounds of copper(I) halides with carbon monoxide, alkali chlorocuprates, complex ammoniacates of copper(I) cyanide, potassium tricyanocuprate(I), double salts with copper(I) thiocyanate, copper(I) acetate, copper(I) sulfide, complex double sulfides of copper(I) sulfide, alkali polysulfides, copper(II) chloride, copper(II) bromide, copper(II) sulfide, copper(II) nitrite, copper(II) thiocyanate, copper(II) cyanide, copper(II) acetate, copper dithiocarbamate, complex ammoniacates of copper(II) salts, copper(I) oxide, metallic cerium, cerium dioxide, cerium(III) chloride, cerium chloride, cerium chlorocomplex salts, cerium nitrate, cerium nitrato salts, cerium sulfate, cerium carbonate, cerium oxalate, cerium sulfides, vanadium oxide, vanadium chloride, vanadium sulfates, molybdenum oxides, molybdenum chloride, molybdenum sulfide, molybdenum fluoride, molybdates, molybdenum complex acido salts, powdered managnese, manganese dioxide, potassium permanganates, manganese dithiocarbamates, manganese acetate, the manganese derivatives corresponding to the above copper compounds, iron oxides, iron(II) and iron(III) salts, complex iron salts, cobalt oxides, cobalt(II) salts, cobalt complex salts, and double and complex vanadium salts.
Dependencies are inferred from the claim text.