Preparation of pigmentary form of quinacridone pigments
AssigneeE. I. Du Pont de Nemours and Company
InventorEdward E. Jaffe
Life of this patent
Estimating the term…
Abstract
Pigmentary grade quinacridone pigments are prepared from crude quinacridone by conversion to aggregated low crystallinity quinacridones followed by milling the aggregated low crystallinity quinacridone in the presence of a liquid which wets the pigment and can improve the crystallinity of quinacridone at 10.degree. to 60.degree. C. Suitable quinacridones include ##STR1## and mixtures thereof with up to 15 wt. % of ##STR2## where R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 R.sup.6 are hydrogen, fluorine, chlorine, bromine, methyl or methoxy; R.sup.7, R.sup.9 and R.sup.10 are hydrogen or chlorine; and R.sup.8 is hydrogen, chlorine, bromine, nitro, alkyl groups of 1 to 5 carbon atoms, alkoxy groups of 1 or 2 carbon atoms or benzoylamino, and m is an integer of from 1 to 4.
Claims11
A process of preparing pigmentary grade quinacridone from crude quinacridone consisting essentially of a quinacridone or mixture of quinacridones of the formula ##STR5## and mixtures thereof, with 0 to 75 weight percent of unsubstituted quinacridone and 0 to 15 wt. % of a quinacridone of the formula ##STR6## where R.sup.1, and R.sup.2 are fluorine, chlorine, bromine, methyl or methoxy;
- R.sup.7, R.sup.9, and R.sup.10 are hydrogen or chlorine;
- R.sup.3, R.sup.4, R.sup.5, and R.sup.6 are hydrogen, fluorine, chlorine, bromine, methyl, or methoxy;
- and R.sup.8 is hydrogen, chlorine, bromine, nitro, alkyl groups of 1 to 5 carbon atoms, alkoxy groups of 1 or 2 carbon atoms or benzoylamino, and m is an integer of from 1 to 4 by converting the crude quinacridone to a low crystallinity aggregated form, followed by milling the low crystallinity quinacridone in a water miscible organic liquid which is effective in improving the crystallinity of quinacridone particles containing up to an equal amount of water present in an amount sufficient to give a fluid slurry and recovering a pigmentary product.
Dependencies are inferred from the claim text.