A process for the purification of an aqueous solution wherein said aqueous solution initially contains (1) a sulphate, a carbonate and a hydroxide or hydrogen carbonate of one of the alkali metals sodium or potassium, and (2) at least one of the metals selected from the group consisting of vanadium, uranium and molybdenum in the form of sodium or potassium salts, and (3) inorganic and/or organic impurities, said process comprising the steps of:
- (a) reacting at a temperature up to the boiling point temperature of said aqueous solution containing the metal salts with lime added to the solution in an amount within the range of 0.1 to 20 times the stoichiometric amount required to convert any carbonates to hydroxides plus the amount taken up in the precipitation of insoluble compounds of calcium to form a precipitate of calcium carbonate and other insoluble organic and inorganic calcium salts in a hydroxide-enriched liquor;
- (b) separating the precipitate from the hydroxide-enriched liquor;
- (c) washing the separated precipitate to form a wash liquor;
- (d) mixing said wash liquor and said hydroxide-enriched liquor;
- (e) concentrating the hydroxide-enriched liquor and wash liquor mixture to a hydroxide content which does not exceed 50% by weight to precipitate alkali metal sulphate, leaving a mother liquor;
- and
- (f) separating the alkali metal sulphate precipitate from the mother liquor.