Contact lens containing a fluorinated telechelic polyether
AssigneeMinnesota Mining and Manufacturing Company
InventorsDavid E. Rice, Jay V. Ihlenfeld
Life of this patent
Estimating the term…
Abstract
Ophthalmic devices of telechelic perfluorinated polyethers, and polymers and compositions for making such devices are disclosed. The devices possess improved oxygen permeability.
Claims14
An ophthalmic device selected from the group consisting of a contact lens and a corneal implant and comprising a polymer of a telechelic perfluoropolyether having a backbone of perfluorooxyalkylene units, a number average molecular weight between about 500 and 15,000, and at least one polymerizable ethylenically unsaturated group wherein said telechelic perfluoropolyether has the formula Q--X--Y--C.sub.k F.sub.2k O).sub.p (C.sub.q F.sub.2q --Z wherein p represents the number of --C.sub.k F.sub.2k O-- subunits in said backbone and is an integer of from 3 to 200, q is an integer of from 1 to 4, and k may be the same of different within each of said --C.sub.k F.sub.2k O-- subunits and is an integer of from 1 to 4
- wherein Q is selected from ##STR18## wherein R is selected from hydrogen or methyl;
- wherein X is selected from (E) a covalent bond, ##STR19## wherein R.sup.1 is selected from a divalent aliphatic group having from 2 to 14 carbon atoms, a divalent 5- or 6-membered cyclic group having from 5 to 14 carbon atoms, or an arylene group having from 6 to 14 carbon atoms, and a in an integer of from 2 to 12;
- wherein Y is selected from (J) --CH.sub.2).sub.b, ##STR20## wherein R.sup.2 is a lower alkyl group having 1 to 4 carbon atoms, a is an integer of from 2 to 12, and b is an integer of from 1 to 12;
- provided that when
- (1) Q is (A), then X is selected from (E), (F), or (G) and Y is selected from (J), (K), or (L);
- (2) Q is (B), then X is selected from (E), (F), or (G) and Y is selected from (J), (K), or (L);
- (3) Q is (C) then either
- (i) X is (E) and Y is (M), or
- (ii) X is selected from (E), (F), (G), (H), or (I) and Y is selected from (J), (K), or (L);
- and
- (4) Q is (D) then either
- (i) X is (E) and Y is (M), or
- (ii) X is selected from (H) or (I) and Y is selected from (J), (K), or (L);
- and
- wherein Z is selected from --OC.sub.k F.sub.2k+1, or Q--X--Y-- wherein Q, X, Y and k are as defined above.
An ophthalmic device selected from the group consisting of a contact lens and a corneal implant and comprising the polymerization product of a composition of
- I. from 50 to 88 weight percent of a telechelic perfluoropolyether having a formula selected from ##STR22## wherein R is hydrogen or methyl, m and n are numbers providing a number average molecular weight of 500 to 15,000 to the backbone of said telechelic perfluoropolyether and have a value of 1 to 120 and a sum of 7 to 120, and wherein the ratio m/n is from 0.2 to 5;
- II. from 10 to 48 weight percent of a first monomer copolymerizable with said telechelic perfluoropolyether, said first monomer being selected from methyl methacrylate, ethyl methacrylate, or cyclohexyl methacrylate;
- and
- III. from 2 to 10 weight percent of an ethylenically unsaturated monomer having hydrophilic group copolymerizable with the telechelic perfluoropolyether.
Dependencies are inferred from the claim text.