Aromatic polyols made from recycled polyethylene terephthalate waste streams, alkylene glycol and dibasic acid waste streams
AssigneeTexaco Inc.
InventorMichael E. Brennan
Life of this patent
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Abstract
Mixtures of aromatic polyols containing ester functionalities suitable for use as polyol extenders in rigid foams prepared by reacting dibasic acid residues with an alkylene glycol residue, the reaction product of which is reacted with recycled polyethylene terephthalate are described. Surprisingly, the process is non-catalytic. These novel polyols may be blended with conventional polyols to yield excellent rigid foams, thus serving as useful polyol extenders.
Claims18
A mixture of aromatic polyols having hydroxyl and ester functionalities for use in preparing rigid foams, being produced by the process comprising
- a. esterifying, in the absence of a catalyst, a residue from dibasic acid manufacture which comprises one or more acids from the group consisting of glutaric acid, succinic acid and adipic acid, with an alkylene glycol to produce a polyester polyol and
- b. transesterifying, in the absence of a catalyst, recycled polyethylene terephthalate with the polyester polyol reaction product from the previous step.
A mixture of aromatic polyols having hydroxyl and ester functionalities for use in preparing rigid foams, being produced by the process comprising
- a. esterifying, in the absence of a catalyst, a residue from dibasic acid manufacture which comprises one or more acids selected from the group consisting of glutaric acid, succinic acid and adipic acid, with an alkylene glycol waste stream containing alkylene glycols of the formula ##STR5## where R is hydrogen or lower alkyl of 1 to 4 carbon atoms and n is from 1 to 3, to produce a polyester polyol, and
- b. transesterifying, in the absence of a catalyst, recycled polyethylene terephthalate with the polyester polyol reaction product from the previous step,
- such that the reactions are conducted at a temperature between 140.degree. to 220.degree. C. and in which the average hydroxyl number of the resultant polyol mixture is between 100 and 400.
A method for making a mixture of aromatic polyols having hydroxyl and ester functionalities for use in preparing rigid foams, comprising
- a. esterifying, in the absence of a catalyst, a residue from dibasic acid manufacture which comprises one or more acids from the group consisting of glutaric acid, succinic acid and adipic acid, with an alkylene glycol to produce a polyester polyol, and
- b. transesterifying, in the absence of a catalyst, recycled polyethylene terephthalate with the polyester polyol reaction product from the previous step.
A rigid polyurethane foam obtained by reacting in the presence of a blowing agent and a catalyst of polyurethane formation an organic polyisocyanate and a polyol blend comprising
- a. from about 5 to 100 percent by weight of a mixture of aromatic polyols having ester functionalities which is the reaction product from
- (1) esterifying, in the absence of a catalyst, a residue from dibasic acid manufacture which comprises one or more acids from the group consisting of glutaric acid, succinic acid and adipic acid, with an alkylene glycol to produce a polyester polyol and
- (2) transesterifying, in the absence of a catalyst, recycled polyethylene terephthalate with the polyester polyol reaction product from the previous step, and
- b. from about 95 to 0 percent by weight of a nitrogen-containing polyol which is the reaction product from
- (1) reacting one mole of phenol or nonylphenol with one to 2 moles of diethanolamine to give a Mannich reaction product and
- (2) subsequently reacting one mole of the Mannich reaction product with 2 to 3 moles of propylene oxide.
A rigid polyisocyanurate foam which is obtained by reacting in the presence of a blowing agent and a trimerization catalyst of polyisocyanate formation, an organic polyisocyanate and a mixture of aromatic polyols having ester functionalities which is the reaction product of the process comprising
- a. esterifying, in the absence of a catalyst, a residue from dibasic acid manufacture which comprises one or more acids from the group consisting of glutaric acid, succinic acid and adipic acid, with an alkylene glycol to produce a polyester polyol and
- b. transesterifying, in the absence of a catalyst, recycled polyethylene terephthalate with the polyester polyol reaction product from the previous step.
Dependencies are inferred from the claim text.