Organic pigments
AssigneeHercules Incorporated
InventorsWilliam W. Maslanka, Gavin G. Spence
Life of this patent
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Abstract
Disclosed are novel organic pigments adapted particularly for use as fillers for paper. The organic pigments are finely divided particles obtained by graft copolymerizing an ethylenically unsaturated monomer, such as styrene, onto a water-soluble cationic prepolymer in an aqueous solution and in the presence of a free-radical polymerization initiator.
Claims6
Water-insoluble graft copolymer particles consisting essentially of the free radical catalyzed graft copolmerization product of (1) at least one ethylenically unsaturated monomer and (2) a water-soluble cationic prepolymer having an RSV of about 0.1 to about 2.5 (1 M NaCl, 1%, 25.degree. C.), the prepolymer moiety of the graft copolymer particles being present on the surface of the particles,
- said monomer (1) being selected from the group consisting of methyl alpha-chloroacrylate, ethyl alpha-chloroacrylate, methyl methacrylate, isopropyl methacrylate, phenyl methacrylate, vinyl chloride, acrylonitrile, methacrylonitrile, and monomers having the formula ##STR20## wherein R is hydrogen or methyl, Y is methyl or chlorine, and n is 0, 1, 2, or 3, and said prepolymer (2) being the addition polymerization product of
- (i) about 5 mole percent to 100 mole percent of a cationic monomer selected from the group consisting of 2-vinylpyridinium chloride and 2-vinylpyridinium bromide, and
- (ii) from about 95 mole percent to 0 mole percent of at least one monoethylenically unsaturated amide monomer,
- the amount of prepolymer (2) employed in preparing the graft copolymer particles being from about 1 part to about 25 parts by weight for each 100 parts by weight of monomer (1) employed, said prepolymer moiety of the particles having chemically bonded thereto a cellulose reactive group, said cellulose reactive group being introduced by means of an epihalohydrin.
Water-insoluble graft copolymer particles consisting essentially of the free radical catalyzed graft copolymerization product of (1) at least one ethylenically unsaturated monomer and (2) a water-soluble cationic prepolymer having an RSV of about 0.1 to about 1.0 (1 M NaCl, 1%, 25.degree. C.), the prepolymer moiety of the graft copolymer particles being present on the surface of the particles,
- said monomer (1) being a monomer having the formula ##STR21## wherein R is hydrogen or methyl, Y is methyl or chlorine, and n is 0, 1, 2, or 3, and said prepolymer (2) being the addition polymerization product of
- (i) about 5 mole percent to 100 mole percent of a cationic monomer selected from the group consisting of 2-vinylpyridinium chloride and 2-vinylpyridinium bromide, and
- (ii) from about 95 mole percent to 0 mole percent of at least one monoethylenically unsaturated amide monomer,
- the amount of prepolymer (2) employed in preparing the graft copolymer particles being from about 2 parts to about 10 parts by weight for each 100 parts by weight of monomer (1) employed, said prepolymer moiety of the particles having chemically bonded thereto a cellulose reactive group, said cellulose reactive group being introduced by means of an epihalohydrin.
A process for preparing a latex of graft copolymer particles which comprises graft copolymerizing in aqueous media and in the presence of a free radical initiator (1) at least one ethylenically unsaturated monomer and (2) a water-soluble cationic prepolymer having an RSV of about 0.1 to about 2.5 (1 M NaCl, 1%, 25.degree. C.),
- said monomer (1) being selected from the group consisting of methyl alpha-chloroacrylate, ethyl alpha-chloroacrylate, methyl methacrylate, isopropyl methacrylate, phenyl methacrylate, vinyl chloride, acrylonitrile, methacrylonitrile, and monomers having the formula ##STR22## wherein R is hydrogen or methyl, Y is methyl or chlorine, and n is 0, 1, 2, or 3, and said prepolymer (2) being the addition polymerization product of
- (i) about 5 mole percent to 100 mole percent of a cationic monomer selected from the group consisting of 2-vinylpyridinium chloride and 2-vinylpyridinium bromide, and
- (ii) from about 95 mole percent to 0 mole percent of at least one monoethylenically unsaturated amide monomer,
- the amount of prepolymer (2) employed in preparing the graft copolymer particles being from about 1 part to about 25 parts by weight for each 100 parts by weight of monomer (1) employed, said prepolymer, prior to graft polymerization, being reacted with a compound that provides the prepolymer with cellulose reactive groups, said compound being an epihalohydrin.
A process for preparing a latex of graft copolymer particles which comprises graft copolymerizing in aqueous media and in the presence of a free radical initiator (1) at least one ethylenically unsaturated monomer and (2) a water-soluble cationic prepolymer having an RSV of about 0.1 to about 1.0 (1 M NaCl, 1%, 25.degree. C.)
- said monomer (1) being a monomer having the formula ##STR23## wherein R is hydrogen or methyl, Y is methyl or chlorine, and n is 0, 1, 2, or 3, said prepolymer (2) being the addition polymerization product of
- (i) about 5 mole percent to 100 mole percent of a cationic monomer selected from the group consisting of 2-vinylpyridinium chloride and 2-vinylpyridinium bromide and
- (ii) from about 95 mole percent to 0 mole percent of at least one monomethylenically unsaturated amide monomer,
- the amount of prepolymer (2) employed in preparing the graft copolymer particles being from about 2 parts to about 10 parts by weight for each 100 parts by weight of monomer (1) employed, said prepolymer, prior to graft polymerization, being reacted with a compound that provides the prepolymer with cellulose reactive groups, said compound being an epihalohydrin.
Dependencies are inferred from the claim text.