Composite inorganic structures and process of producing same

A process for making a composite inorganic article which comprises forming a first slurry composed of inorganic particles and a freeze-sensitive colloidal ceramic sol, forming at least a second slurry composed of diffferent inorganic particles having a different mass thermal coefficient of expansion than the inorganic particles contained in the first slurry and a freeze-sensitive colloidal ceramic sol which can be the same as or different from the colloidal sol used in said first slurry, bringing the slurries into physical contact with each other in a layered fashion without substantial intermixing thereof, simultaneously freezing the layered slurries in a cooling media while in contact with each other to form a unified structure that is characterized by an interfacial bond of sufficient strength to withstand temperatures of at least about 3000.degree. F. and having high thermal shock resistance and wherein the difference between the two mass thermal coefficients of expansion, although sufficient to cause disruption of the interfacial bond resulting from conventional processes for producing composite inorganic articles, does not cause disruption of the interfacial bond at temperatures of at least about 3000.degree. F.