Cellulosic molding and spinning compound with low contents of low-molecular decomposition products
AssigneeAkzo N.V.
InventorsAlexander Brandner, Hand G. Zengel
Life of this patent
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Abstract
Molding compositions containing cellulose, 95-50% of a tertiary amine oxide, and up to 25% of a non-solvent also up to 10% of other polymers, all proportions relative to the weight of the composition and as additive, 0.01 up to 0.5% by weight, relative to the tertiary amine oxide, of an organic compound with a minimum of four carbon atoms and a minimum of two conjugated double bonds and a minimum of two groups in the form of hydroxyl and/or amino groups which, in turn, have a minimum of one unsubstituted hydrogen atom and/or contain glycerol aldehyde.
Claims15
Molding or spinning substance, comprising by weight 4.99-25% cellulose, 95-50% of a tertiary amine oxide, in given instances up to 25% of a non-solvent and up to 10% of other polymers, all proportions relative to the weight of the molding or spinning substance, and as additive, singly or in a mixture, 0.01 up to 0.5% by weight, relative to the tertiary amine oxide, of an organic compound with a minimum of four carbon atoms and a minimum of two conjugated double bonds and a minimum of two groups in the form of hydroxyl and/or amino groups which, in turn, have a minimum of one unsubstituted hydrogen atom and/or contain glycerol aldehyde, said additive being soluble in said tertiary amine oxide as well as its mixture with said non-solvent.
Molding or spinning substance according to claim 1 or claim 28, wherein the organic compound is pyrocatechol, pyrogallol, gallic acid, or the methyl ester, ethyl ester, propylester or isopropyl ester of gallic acid.
Molding or spinning substance according to claim 2 or claim 28, wherein the organic compound is hydroquinone, 4(methylamino)phenol sulfate, N-cyclohexyl-N'-(2-cyanoethyl)-1,4-phenylene diamine or N-cyclohexyl-N'-phenyl-1,4-phenylene diamine.
Dependencies are inferred from the claim text.