Cyclic perfluoroaliphatic-disulfonic acid anhydrides and sulfonamide derivatives thereof
AssigneeMinnesota Mining and Manufacturing Company
InventorFred E. Behr
Life of this patent
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Abstract
Cyclic perfluoroaliphaticdisulfonic acid anhydrides, sulfonamide derivatives thereof, a process for making the same, curable compositions containing cyclic perfluoroaliphaticdisulfonic acid anhydrides or sulfonamide derivatives thereof and cationically-sensitive monomers, and a process for using cyclic perfluoroaliphaticdisulfonic acid anhydrides or sulfonamide derivatives thereof as catalysts for the cure of cationically-sensitive monomers.
Claims10
Sulfonamides, useful as latent catalysts for the polymerization of cationically-sensitive monomers, comprising the reaction product of at least one cyclic anhydride of perfluoroaliphaticdisulfonic acids, having the formula:
- ##STR10## wherein R.sub.f is perfluoroalkylene having 2 to 5 catenary carbon atoms or perfluorocycloalkylene having 4 to 7 ring atoms, R.sub.f optionally being substituted by one or more straight chain, branched, or cyclic perfluoroalkyl groups of 1 to 12 carbon atoms, with R.sub.f having a total of up to 14 carbon atoms, together with at least one protonic nitrogenous base having a pk.sub.b of less than about 13.2.
Sulfonamides, useful as latent catalysts for the polymerization of cationically-sensitive monomers, comprising compounds having the formula:
- R.sup.1 R.sup.2 NSO.sub.2 R.sub.f SO.sub.3.sup.- H.sub.2 N.sup.+ R.sup.1 R.sup.2
- wherein R.sub.f is perfluoroalkylene having 2 to 5 catenary carbon atoms or perfluorocycloalkylene having 4 to 7 ring atoms, R.sub.f optionally being substituted by one or more straight chain, branched, or cyclic perfluoroalkyl groups of 1 to 12 carbon atoms, with R.sub.f having a total of up to 14 carbon atoms, and each R.sup.1 and R.sup.2 is independently hydrogen, or a monovalent organic radical which can be the same as or different from any other R.sup.1 or R.sup.2, or each R.sup.1 and R.sup.2 bonded to the same N atom can combine with one another to form a cyclic structure containing the N atom, and R.sup.1 and R.sup.2 can contain from 1 to about 20 carbon atoms, can be straight chain, branched or cyclic, can be saturated, unsaturated or aromatic, can contain skeletal or catenary hetero atoms other than carbon and can be unsubstituted or substituted with non-interfering moieties.
Curable compositions, comprising cationically-sensitive monomers and a catalytically effective amount of cyclic anhydride of perfluoroaliphaticdisulfonic acids, having the formula:
- ##STR11## wherein R.sub.f is perfluoroalkylene having 2 to 5 catenary carbon atoms or perfluorocycloalkylene having 4 to 7 ring atoms, R.sub.f optionally being substituted by one or more straight chain, branched, or cyclic perfluoroalkyl groups of 1 to 12 carbon atoms, with R.sub.f having a total of up to 14 carbon atoms.
A process for polymerizing cationically-sensitive monomers using a cyclic anhydride of perfluoroaliphaticdisulfonic acids, having the formula:
- ##STR12## wherein R.sub.f is perfluoroalkylene having 2 to 5 catenary carbon atoms or perfluorocycloalkylene having 4 to 7 ring atoms, R.sub.f optionally being substituted by one or more straight chain, branched, or cyclic perfluoroalkyl groups of 1 to 12 carbon atoms, with R.sub.f having a total of up to 14 carbon atoms, comprising the steps of:
- (a) mixing with said monomers a catalytically effective amount of said cyclic anhydride or sulfonamide derivative thereof, thereby forming a mixture;
- and
- (b) allowing said mixture to polymerize or heating said mixture to effect polymerization thereof.
Dependencies are inferred from the claim text.