Raney alloy methanation catalyst
AssigneeOlin Corporation
InventorThomas J. Gray
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Abstract
A methanation process utilizing an improved catalyst for the conversion of CO, CO.sub.2 and mixtures thereof to CH.sub.4 is disclosed. The catalyst comprises a monolithic mesh type structure of a nickel alloy having an integral Beta phase Raney coating on its outer surfaces. When used, substantially higher reactant flow rates and lower operating temperatures are possible as compared to conventional fluidized bed granular catalysts.
Claims10
A monolithic catalyst comprised of a metallic substrate with an integral Raney metal exterior surface, said surface being predominantly derived from an adherent Ni.sub.x M.sub.1-x Al.sub.3 Beta structured crystalline precursory layer, where said layer is integral with and derived from said substrate, M is a catalytic enhancer selected from the group consisting of molybdenum, titanium, tantalum, ruthenium or mixtures thereof and where x, the weight fraction of nickel in the combined weight of Ni and M, is within the range of from about 0.80 to about 0.95.
Dependencies are inferred from the claim text.