Adiabatic pressure swing absorption process for removing low concentrations of oxygen from mixed gas streams
AssigneeAir Products and Chemicals, Inc.
InventorsAugustine I. Dalton, Jr., John J. Sheridan, III, David A. Zagnoli
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Abstract
An adiabatic pressure swing absorption process is disclosed for the removal of essentially all oxygen contained in an inert gas stream in minor amounts. The oxygen is absorbed and desorbed adiabatically from a dioxygen sorbent. Optionally, an inert purge gas can be utilized to improve the desorption of oxygen from the dioxygen sorbent. The process utilizes at least two switching beds of the dioxygen sorbent in which one bed is in an absorbing mode while the other bed is in a desorbing mode.
Claims19
A process for removing oxygen from an oxygen-containing inert gas stream by absorption of the oxygen into a dioxygen absorbent in an adiabatic pressure swing absorption process wherein the process is designed to operate below the temperature of decomposition of the absorbent, comprising the steps of:
- (a) introducing an oxygen-containing inert gas stream into a first bed of a dioxygen absorbent at a temperature on the isotherm of the particular absorbent which will allow for adiabatic absorption without degradation of the absorbent;
- (b) adiabatically absorbing the oxygen content of said insert gas stream of said dioxygen absorbent, while removing an essentially oxygen-free inert gas from said bed;
- (c) terminating said absorption on said first bed before oxygen breakthrough in said bed;
- (d) switching the flow of the inert gas stream to a second dioxygen absorbent bed for adiabatic absorption of the oxygen content of said stream while removing an essentially oxygen-free inert gas from said bed;
- (e) desorbing said first bed adiabatically by reducing the pressure in said bed and by utilizing the heat of absorption to drive absorbed oxygen off of said dioxygen absorbent;
- (f) repressurizing said first bed with essentially pure oxygen-free inert gas from the downstream flow of product gas from said second bed;
- (g) terminating said absorption on said second bed before oxygen breakthrough in said bed;
- (h) switching the flow of the inert gas stream back to the first dioxygen absorbent bed, while desorbing the second bed as described in step (e) above;
- (i) repressurizing the second bed with essentially pure oxygen-free inert gas from the downstream flow of product gas from said first bed;
- (j) cyclically repeating steps (a) through (i) for the production of an essentially oxygen-free inert gas.
A process for removing essentially all oxygen from a crude argon gas stream containing a minor amount of oxygen by absorption of the oxygen on a dioxygen absorbent in an adiabatic pressure swing absorption process utilizing at least three absorbent beds wherein the process is designed to operate below the temperature of decomposition of the absorbent, comprising the steps of:
- (a) introducing a crude argon and oxygen gas stream into a first bed of an oxygen absorbent comprising a dioxygen compound, which chemically absorbs and desorbs oxygen reversibly, selected from the class comprising metal chelates of Group III-VIII metals which bind oxygen while preserving the oxygen to oxygen bond at a temperature on the isotherm of the particular absorbent which will allow for adiabatic absorption without degradation of the absorbent;
- (b) adiabatically absorbing essentially the entire oxygen content of said crude stream on said absorbent in said first bed, while removing a pure argon stream from said bed as a product stream;
- (c) pressurizing a second dioxygen absorbent containing bed with pure argon gas from said product stream;
- (d) terminating said absorption on said first bed before oxygen breakthrough;
- (e) switching the flow of crude argon to said second dioxygen absorbent containing bed for adiabatic absorption of the oxygen content of said crude argon, while removing a pure product argon stream from said second bed;
- (f) desorbing said first bed by reducing the pressure in said bed, utilizing the heat of absorption built up in said bed to provide for the endothermic heat of oxygen desorption to drive absorbed oxygen off of the dioxygen absorbent;
- (g) pressurizing a third dioxygen absorbent containing bed with pure argon gas from the product stream of said second bed;
- (h) switching the flow of crude argon to said third bed for adiabatic absorption of oxygen and removal of a pure argon product from said bed, while desorbing said second bed as set forth in step (f) above and repressurizing said first bed as set forth in step (g) with the product from the third bed;
- (i) repeating the preceding sequence for continuous argon-oxygen separation.
Dependencies are inferred from the claim text.