Tackified crosslinked acrylic adhesives
AssigneeMinnesota Mining and Manufacturing Company
InventorsJoanne P. Kealy, Robert E. Zenk
Life of this patent
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Abstract
Pressure-sensitive adhesive tape is made by coating a sheet backing with a solution of iso-octyl acrylate:acrylic acid copolymer containing a tackifying rosin ester and an anti-oxidant, evaporating the solvent, and crosslinking the adhesive. The resultant adhesive has an excellent balance of the tack, peel adhesion, and shear properties, even at 70.degree. C., and adheres well to low energy surfaces.
Claims7
Normally tacky and pressure-sensitive adhesive tape comprising a sheet material having, on at least one surface, a thin layer of normally tacky and pressure-sensitive adhesive containing trace amounts of solvent and consisting essentially of an at least substantially surfactant-free blend of (a) a crosslinked pressure-sensitive copolymer of 100 parts by weight of monomers consisting essentially of iso-octyl acrylate and 3-7 parts by weight of acrylic acid, said copolymer, prior to crosslinking being soft, tacky, and having an inherent viscosity on the order of 0.75-1.5 dl/g, (b) a small amount of an antioxidant that is based on either a hindered phenol or a sulfur-containing organo-metal salt, and (c) a tackifying rosin ester, said adhesive having the properties of (1) a rolling ball tack value of less than 6 cm, (2) an ability to bond firmly to stainless steel, ABS terpolymer, low density polyethylene, and isotactic polypropylene, and (3) a shear value of at least 5,000 minutes at 70.degree. C.
Dependencies are inferred from the claim text.