Method of making and improved compositions for an initially erasable ink for a ball point writing instrument
AssigneeScripto, Inc.
InventorFrank A. Muller
Life of this patent
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AssigneeScripto, Inc.
InventorFrank A. Muller
Estimating the term…
An initially erasable ink composition for a ball point writing instrument which ink is characterized by its initial erasability by ordinary pencil erasers when applied by a ball point writing instrument to an absorbent paper-like writing surface and which thereafter develops permanence. The ink composition comprises polar elastomers, such as butadiene/acrylonitrile copolymer rubbers and vinyl acetate/ethylene copolymer rubbers, and mixtures thereof, either alone or in admixture with cis-1, 4-polyisoprene (natural rubber or synthetic nature rubber), pigment, and a solvent system. The polar elastomer is present in the range of about 14-25% by weight of the ink and the pigment is present in amount sufficient to impart color and intensity to a trace of the ink when applied to a substrate such as paper. The solvent system essentially comprises a volatile component having a boiling point less than about 180.degree. C. and an essentially non-volatile component which includes pigment vehicle having a boiling point greater than about 300.degree. C. and low viscosity plasticizer having a boiling point greater than 180.degree. C. but less than 300.degree. C., the solvent system being present in amount sufficient to impart a final ink viscosity in the range of about 1.5 million cps.
In a ball point writing instrument containing an ink capable of depositing a trace on an absorbent, paper-like writing surface having minute voids therein, said trace being characterized by initial erasability thereof by ordinary pencil erasers and the capability of developing permanence over a period of time, said ink comprising pigment, a polar elastomer, said polar elastomer having a selected molecular weight range of about 90,000 to 1,000,000 and a selected Mooney viscosity range of about 15 to 60 and requiring no mastication for use in said ink, and a solvent system, said solvent system comprising a volatile component having a boiling point less than about 180.degree. C. and an essentially non-volatile component which includes pigment vehicle having a boiling point greater than about 300.degree. C. and low viscosity plasticizer having a boiling point greater than 180.degree. C. but less than 300.degree. C., the solvent system being present in amount sufficient to impart a final ink viscosity in the range of about 1.5 million cps.
The method of making an ink composition for ball point pen writing instrument, which composition when applied by the pen as a trace on a porous substrate such as paper will exhibit the characteristic of initial erasability by ordinary pencil eraser but developing indelibility with time, which comprises the steps of:
In a pressurized ball point writing instrument containing an ink capable of depositing a trace on an absorbent, paper-like writing surface having minute voids therein, said trace being characterized by initial erasability thereof by ordinary pencil erasers and the capability of developing permanence over a period of time, said ink having the consistency of a relatively loose-structured gel and comprising pigment, a polar elastomer having a Mooney viscosity of about 15-60 and a molecular weight in the range of about 90,000-1,000,000 and a solvent system;
Dependencies are inferred from the claim text.