Process for the preparation of pyridine and substituted pyridines
AssigneeRhone-Poulenc Specialites Chimiques
InventorsGeorges Cordier, Patrick Leroux
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AssigneeRhone-Poulenc Specialites Chimiques
InventorsGeorges Cordier, Patrick Leroux
Estimating the term…
The present invention relates to a process for the preparation of pyridine and substituted pyridines, in the vapor phase. These compounds are obtained by heating, at a temperature of 200.degree. to 500.degree. C., in the vapor phase: piperidine or piperidine substituted by one or more lower alkyl radicals; 1,5-diaminopentane; 1,5-diaminopentane containing, in its hydrocarbon part, from 1 to 3 linear or branched alkyl radicals having from 1 to 4 carbon atoms; or compounds such as: N,N'-bis-(piperidin-2-yl)hydrazines, in the presence of a catalyst consisting of palladium, platinum or ruthenium deposited on a macroporous solid. The products obtained by the process according to the invention have various uses. Pyridine is used in particular as a solvent. .beta.-Picoline (or 3-methylpyridine) is used for the preparation of nicotinic acid or nicotinamide, used in pharmacy and in nutrition.
Process for preparation of compounds of the following general formula (I):
Dependencies are inferred from the claim text.