# US 4,400,760 A · Dielectric ceramic composition having a base of barium titanate, lithium oxide and cadmium fluoride, a capacitor in which a composition of this type is employed, and a method of production of said composition

> Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt

- Number: US 4,400,760 A
- Document ID: US4400760A
- Status: Granted
- Kind: A
- Application number: 06/381,834
- Filed: 1982-05-25
- Granted: 1983-08-23
- Earliest claimed: 1981-05-26
- Assignees: LCC.CICE-Compagnie Europeenne de Composants Electroniques
- Inventors: Alain Lagrange; Alain Beauger
- Web page: https://patentgrep.com/patent/US4400760A

## CPC

- C04B 35/4682: {based on BaTiO3 perovskite phase}
- H01G 4/1227: {based on alkaline earth titanates}
- C04B: LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE {(roofing granules E04D7/005)}; CERAMICS (devitrified glass-ceramics C03C10/00); REFRACTORIES; TREATMENT OF NATURAL STONE
- H01G: CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE (selection of specified materials as dielectric H01B3/00; capacitors having potential barriers H10D1/62, H10K10/10)

## Abstract

A dielectric ceramic composition which has excellent electrical properties and can be sintered at a temperature within the range of 750.degree. C. to 1000.degree. C. contains 85 to 97% by weight of barium titanate, 0.5 to 2.5% by weight of lithium oxide and 2.5 to 12% by weight of cadmium fluoride.

## Claims

### Claim 1

A ceramic consisting essentially of a dielectric composition having 85% to 97% by weight of barium titanate and the balance being, 0.5% to 2.5% by weight of lithium oxide and 2.5% to 12% by weight of cadmium fluoride wherein molar ratio of TiO.sub.2 /BaO in said barium titanate is higher than or equal to 0.97 and lower than or equal to 0.98.

### Claim 2 (depends on 1)

The dielectric composition according to claim 1, wherein the lithium oxide is obtained from a lithium salt which is capable of liberating said oxide at high temperature.

### Claim 3 (depends on 2)

The dielectric composition according to claim 2, wherein the lithium salt is selected from lithium nitrates, sulfates or carbonates.

### Claim 4 (depends on 1)

An electric capacitor comprising at least one dielectric layer covered by conductive metal plates, wherein the dielectric layer is constituted by a composition according to claim 1.

### Claim 5

A method of fabrication of an electric capacitor, wherein said method consists essentially of producing a calcined powder containing 85% to 97% by weight of barium titanate, 2.5% to 12% by weight of cadmium fluoride, and 0.5% to 2.5% by weight of lithium oxide said lithium oxide being introduced in the form of a salt and the ratio of TiO.sub.2 /BaO in said barium titanate is higher than or equal to 0.97 and lower than or equal to 0.98, and then fabricating the capacitor by means of said calcined powder in a manner known per se, said capacitor being provided with a dielectric ceramic layer which has been sintered at a temperature higher than or equal to 750.degree. C. at which the lithium salt is decomposed and gives rise in particular to the formation of lithium oxide.