# US 4,400,456 A · Thermo-developable type diazo copying material > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 4,400,456 A - Document ID: US4400456A - Status: Granted - Kind: A - Application number: 06/295,036 - Filed: 1981-08-21 - Granted: 1983-08-23 - Earliest claimed: 1980-08-29 - Assignees: Ricoh Company, Ltd. - Inventors: Tsutomu Matsuda; Shigeru Kusakata - Web page: https://patentgrep.com/patent/US4400456A ## CPC - G03C 1/61: with non-macromolecular additives - G03C: PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES (for photomechanical purposes G03F); PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY (photographic processes characterised by the use or manipulation of apparatus classifiable per se in subclass G03B, see G03B; photomechanical production of textured or patterned surfaces G03F; electrophotography, magnetography G03G) ## Abstract A thermo-developable type diazo copying material is disclosed comprising a substrate and a photosensitive layer, formed thereon, consisting essentially of a diazo compound, a coupler and a color assistant, wherein said color assistant is at least a member selected from the group consisting of fatty acid amides having the general formula I: R.sup.1 CONH.sub.2 (wherein, R.sup.1 is a saturated or unsaturated aliphatic hydrocarbon group having 5 to 24 carbon atoms), N-substituted fatty acid amides having the general formula II: R.sup.1 CONHR.sup.2 (wherein, R.sup.1 is the same as defined above and R.sup.2 is an alkyl group having 1 to 5 carbon atoms, substituted or non-substituted phenyl group or substituted or non-substituted cyclohexyl group) and N-substituted fatty acid amides having the general formula III: R.sup.1 NHCOR.sup.2 (wherein, R.sup.1 and R.sup.2 are the same as defined above respectively), and said coupler is encapsulated with a member selected from the group consisting of non-polar wax-like substances having a melting point of 50.degree. to 150.degree. C. and hydrophobic vinyl resins having a softening point of 50.degree. to 150.degree. C. ## Claims ### Claim 1 A thermally developable, diazo-type, copying material comprising a substrate and a photosensitive layer formed on said substrate, said photosensitive layer consisting essentially of a diazonium compound suitable for use in a two component diazotype copying material, an azo coupling component and a color assistant, wherein said color assistant is at least one member selected from the group consisting of fatty acid amides having the formula: R.sup.1 CONH.sub.2 wherein R.sup.1 is a saturated or unsaturated aliphatic hydrocarbon group having 5 to 24 carbon atoms, N-substituted fatty acid amides having the formula: R.sup.1 CONHR.sup.2 wherein R.sup.1 is the same as defined above and R.sup.2 is an alkyl group having 1 to 5 carbon atoms, phenyl, substituted phenyl, cyclohexyl or substituted cyclohexyl, and N-substituted fatty acid amides having the formula: R.sup.1 NHCOR.sup.2 wherein R.sup.1 and R.sup.2 are the same as defined above respectively; and wherein said coupling component is in the form of fine particles encapsulated with an encapsulating material to form capsules, said encapsulating material being selected from the group consisting of non-polar wax-like substances having a melting point in the range of 50.degree. to 150.degree. C. and hydrophobic vinyl resins having a softening point in the range of 50.degree. to 150.degree. C. ### Claim 2 (depends on 1) A copying material as claimed in claim 1 wherein the particle diameters of said capsules are in the range of 1 to 50.mu.. ### Claim 3 (depends on 1) A copying material as claimed in claim 1 wherein said wax-like substance is selected from the group consisting of paraffin wax, polyethylene wax, polypropylene wax and chlorinated paraffin, said vinyl resin is selected from the group consisting of vinyl acetate-methyl methacrylate copolymer, vinyl acetatebutyl methacrylate-styrene copolymer, vinyl acetate-lauryl methacrylate copolymer, butadiene-styrene-methyl methacrylate copolymer, vinyl acetate-styrene-hydroxyethyl methacrylate copolymer, methyl methacrylate-styrene copolymer, polyvinyl chloride, vinylidene chloride-methyl methacrylate copolymer, vinyl acetate-vinyl chloride copolymer, vinyl acetate-styrene copolymer, polystyrene and polyvinylidene chloride. ### Claim 4 (depends on 1) A copying material as claimed in claim 1 wherein the weight ratio of said diazonium compound: said coupler excluding said encapsulating material: said color assistant is in the range of 1:0.1 to 10:0.1 to 20, and the weight ratio of said coupler: said encapsulating material is in the range of 1:0.5 to 10. ### Claim 5 (depends on 1) A copying material as claimed in claim 1 wherein said diazonium compound is selected from the group consisting of compounds having the formula: ##STR4## wherein R.sup.3 and R.sup.4 are each an alkyl group having 1 to 5 carbon atoms, R.sup.5 and R.sup.6 are each a substituted or non-substituted alkyl, oxyalkyl, aralkyl or cycloalkyl group, or R.sup.5 and R.sup.6 may form a heterocyclic ring together with the nitrogen atom to which they are bonded, and X represents an anion; and compounds having the formula: ##STR5## wherein R.sup.7 is an alkyl group having 1 to 5 carbon atoms, an alkyl group having oxygen atoms or a carbonyl group in the main chain thereof, or a substituted or unsubstituted phenyl group, R.sup.8 and R.sup.9 are each a substituted or unsubstituted alkyl group, an alkyl group having oxygen atoms or a carbonyl group in the main chain thereof, a oxyalkyl group, an aralkyl group or a cycloalkyl group, or R.sup.8 and R.sup.9 may form a heterocyclic ring together with the nitrogen atom to which they are bonded, Y is a halogen and X is an anion. ### Claim 6 (depends on 1) A copying material as claimed in claim 1 wherein said photosensitive layer is formed on said substrate in an amount in the range of 2.5 to 15 g/m.sup.2. ### Claim 7 (depends on 1) A copying material as claimed in claim 1 wherein said photosensitive layer comprises a first sublayer consisting essentially of said encapsulated coupler and said color assistant, said first sublayer being formed directly on said substrate in an amount of 2 to 10 g/m.sup.2, and a second sublayer consisting essentially of said diazonium compound, said second sublayer being formed directly on said first sublayer in an amount of 0.5 to 5 g/m.sup.2.