# US 4,400,337 A · Method for production of metal magnetic particles

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- Number: US 4,400,337 A
- Document ID: US4400337A
- Status: Granted
- Kind: A
- Application number: 06/337,149
- Filed: 1982-01-05
- Granted: 1983-08-23
- Earliest claimed: 1981-01-10
- Assignees: Hitachi Maxell, Ltd.
- Inventors: Yukihiro Hayashi; Toshinobu Sueyoshi; Shigeo Hirai; Mikio Kishimoto; Katsunori Tashita; Masahiro Amemiya
- Web page: https://patentgrep.com/patent/US4400337A

## CPC

- H01F 1/065: {obtained by a reduction}
- H01F 1/061: {with a protective layer}
- H01F: MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES

## Abstract

A method for the production of uniform acicular metal magnetic particles comprising predominantly iron which have excellent magnetic characteristics and are useful as a recording element for a magnetic recording medium, said method comprising the steps of coating the surface of metal compound particles containing predominantly acicular iron oxyhydroxide or iron oxides with at least one member selected from the group consisting of an aluminum compound and a silicon compound, pelletizing the coated particles, and reducing the pellets with heating under reducing atmosphere, e.g. under hydrogen stream.

## Claims

### Claim 1

A method for the production of acicular metal magnetic particles comprising predominantly iron, which comprises the steps of coating the surface of metal compound particles containing predominantly acicular iron oxyhydroxide or iron oxides with at least one member selected from the group consisting of an aluminum compound and a silicon compound, pelletizing the coated particles to form pellets having an average size of from 0.5 to 30 mm, and reducing the thus produced pellets with heating under reducing atmosphere.

### Claim 2 (depends on 1)

A method according to claim 1, wherein said pelletizing step comprises a tableting method comprising compressing the coated metal compound particles in a dry state under a compression of about 200 to 1,000 kg/cm.sup.2 with a tableting machine.

### Claim 3 (depends on 1)

A method according to claim 1, wherein the coating step is carried out with both an aluminum compound and a silicon compound.

### Claim 4 (depends on 1)

A method according to claim 1, wherein the pellets are subjected to a heat treatment at a temperature of 200.degree. to 1,000.degree. C. before being subjected to the reduction step.

### Claim 5 (depends on 1)

A method according to claim 1, wherein the coated particles are subjected to a heat treatment at a temperature of 200.degree. to 1,000.degree. C. before being subjected to the pelletizing step.

### Claim 6 (depends on 5)

A method according to claim 5, wherein the particles are first coated with an aluminum compound, then the coated particles are subjected to said heat treatment and then the heat treated particles are coated with a silicon compound.

### Claim 7 (depends on 1)

A method according to claim 1, wherein the coating with an aluminum compound is carried out in an amount of 0.01 to 2.0% by weight (calculated as the atomic ratio: Al/Fe), and the coating with a silicon compound is carried out in an amount of 0.1 to 10% by weight (calculated as the atomic ratio: Si/Fe).

### Claim 8 (depends on 1)

A method according to claim 1, wherein said silicon compound is a member selected from the group consisting of aluminum sulfate, aluminum nitrate, aluminum chloride, sodium aluminate and water-soluble aluminates.

### Claim 9 (depends on 1)

A method according to claim 1, wherein said pelletizing step comprises a compression molding method comprising:
(a) dispersing the coated metal compound particles in water; and
(b) dehydrating the particles with compression with a filter press so that the water content of the particles becomes about 60 to 80% by weight.

### Claim 10 (depends on 1)

A method according to claim 1, wherein said pelletizing step comprises an extrusion molding method comprising:
(a) adding water to the coated metal compound particles until the water content thereof becomes about 35 to 45% by weight;
(b) kneading the resultant mixture; and
(c) extrusion molding the mixture into pellet shaped particles.