# US 4,400,315 A · Method of removing phosphate materials from deproteinized cheese whey

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- Number: US 4,400,315 A
- Document ID: US4400315A
- Status: Granted
- Kind: A
- Application number: 06/459,937
- Filed: 1983-01-21
- Granted: 1983-08-23
- Earliest claimed: 1983-01-21
- Inventors: Frank A. Thomas
- Web page: https://patentgrep.com/patent/US4400315A

## CPC

- A23C 21/00: Whey; Whey preparations (concentration, evaporation or drying A23C1/00; milk preparations, milk powder or milk powder preparations in which the chemical composition of the milk is modified by non-chemical treatment A23C9/14; preservation of whey or whey preparations A23B11/80)
- Y10S 530/833: Whey; cheese
- A23C: DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; PREPARATION THEREOF (preservation thereof A23B11/00)
- Y10S: TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

## Abstract

A method is disclosed for removing phosphates from deproteinized cheese whey to improve the handling characteristics of such deproteinized whey. The method includes adjusting the pH of the deproteinized whey, a heating step subsequent to pH adjustment followed by injection of calcium hydroxide to remove dicalcium phosphate as a precipitate. Following a holding period, the precipitate is removed to yield an improved deproteinized whey.

## Claims

### Claim 1

A method for removing phosphates from deproteinized cheese whey comprising the steps of adjusting the pH of the deproteinized whey to between 6.4-7.0, subsequently heating the deproteinized whey to a temperature of at least 150.degree. F. but not more than 180.degree. F., subsequently adding calcium hydroxide to the heated deproteinized whey to precipitate phosphates therefrom, the addition of calcium hydroxide being in an amount sufficient to precipitate substantially all phosphates therefrom but in no event should the concentration exceed about 0.1% by weight based on the solids contained in said deproteinized whey, subsequently holding the thus treated deproteinized whey for a holding period lasting at least two hours to allow the material to cool and permit the further precipitation of dicalcium phosphate and removing the dicalcium phosphate precipitate from the deproteinized whey.

### Claim 2 (depends on 1)

The method set forth in claim 1 wherein said pH is adjusted to a level of between 6.5-6.7.

### Claim 3 (depends on 1)

The invention set forth in claim 1 wherein said heating step is carried out until the deproteinized whey is heated to a temperature of between 160.degree.-180.degree. F.

### Claim 4

A method of preparing a deproteinized cheese whey and improving the handling characteristics thereof by removing phosphates therefrom comprising the sequential steps of:
(a) deproteinizing the whey by employing a membrane impervious to the major portion of the protein molecules contained in the whey and employing the process of ultrafiltration and collecting the permeate as deproteinized whey;
(b) adjusting the pH of the permeate to a level of between 6.5-6.7;
(c) heating the deproteinized whey to a temperature of between 160.degree. F. and 180.degree. F.;
(d) adding sufficient calcium hydroxide to the heated deproteinized whey to precipitate substantially all phosphates therefrom as dicalcium phosphate;
(e) holding the material from step (d) for a period of at least two hours to allow the deproteinized whey to cool and to precipitate further dicalcium phosphate therefrom; and,
(f) removing the precipitate from the deproteinized whey.

### Claim 5 (depends on 4)

The method of claim 4 comprising the further step of partially evaporating the deproteinized whey.