# US 4,400,288 A · Detergent compositions and processes of making thereof

> Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt

- Number: US 4,400,288 A
- Document ID: US4400288A
- Status: Granted
- Kind: A
- Application number: 06/286,443
- Filed: 1981-07-24
- Granted: 1983-08-23
- Earliest claimed: 1980-07-28
- Assignees: The Procter & Gamble Company
- Inventors: Shafiq Dhanani; Ronald MacDonald; James S. Clunie; Maxim C. Brooks
- Web page: https://patentgrep.com/patent/US4400288A

## CPC

- C11D 3/3738: {Alkoxylated silicones}
- C11D 1/72: Ethers of polyoxyalkylene glycols
- C11D 3/0026: {Low foaming or foam regulating compositions}
- C11D 3/373: {containing silicones}
- C11D: DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL

## Abstract

Foam-controlled detergent compositions comprising alkoxylated nonionic surfactant, polydimethylsiloxane foam-controller dispersed therein, and siloxane-oxyalkylene copolymer as dispersing agent therefor, the weight ratio of polydimethylsiloxane to dispersing agent lying in the range from 2:1 to 20:1. The compositions preferably also contain particulate silica in a weight ratio of polydimethylsiloxane to silica of from 20:1 to 200:1.

## Claims

### Claim 1

A foam-controlled detergent composition comprising from 1.5% to 100% of a mixture of:
(a) alkoxylated nonionic surfactant,
(b) polydimethylsiloxane foam controller dispersed in at least part of the alkoxylated nonionic surfactant, and
(c) siloxane-oxyalkylene copolymer as dispersing agent for the polydimethylsiloxane foam controller,
wherein the weight ratio of alkoxylated nonionic surfactant to polydimethylsiloxane foam controller is in the range from 10:1 to 100:1 and the weight ratio of polydimethylsiloxane foam controller to siloxane-oxyalkylene copolymer is in the range from 2:1 to 20:1.

### Claim 2 (depends on 1)

A composition according to claim 1 wherein the polydimethylsiloxane foam controller is dispersed in the nonionic surfactant together with particulate silica in a weight ratio of polydimethylsiloxane to silica in the range from 20:1 to 200:1.

### Claim 3 (depends on 2)

A composition according to claim 2 wherein the weight ratio of alkoxylated nonionic surfactant to polydimethylsiloxane foam controller is in the range from 25:1 to 65:1 and the weight ratio of polydimethylsiloxane foam controller to siloxane-oxyalkylene copolymer is in the range from 5:1 to 15:1.

### Claim 4 (depends on 1)

A composition according to claim 1 wherein the siloxaneoxyalkylene copolymer has the general formula I:
R.sub.a SiY.sub.4-a I
wherein a is 0 or an integer from 1 to 3, R is an alkyl group containing from 1 to 30 carbon atoms, or a group of formula II:
R'(OR').sub.b OR" II
wherein R' is an alkylene group containing from 1 to 6 carbon atoms, b has a value of from 1 to 100; and R" is a capping group which is selected from hydrogen, alkyl, acyl, aryl, alkaryl, aralkyl or alkenyl groups containing up to 20 carbon atoms, sulfate, sulfonate, phosphate, carboxylate, phosphate, borate or isocyanate groups, or mixtures thereof: Y is a group having the formula III: ##STR2## wherein R is as defined above and c has a value from 1 to 200; and wherein at least one R group in the compound has the formula II.

### Claim 5 (depends on 4)

A composition according to claim 4 wherein the siloxane-oxyalkylene copolymer is selected from copolymers having the general formula IV to VII:
R'''.sub.a Si{(OSiMe.sub.2).sub.p (OSiMeG).sub.q OSiMe.sub.2 G}.sub.4-a IV
R'''.sub.a Si{(OSiMe.sub.2).sub.p (OSiMeG).sub.r OSiMe.sub.3 }.sub.4-a V
GMe.sub.2 Si(OSiMe.sub.2).sub.p (OSiMeG).sub.q OsiMe.sub.2 G, and VI
Me.sub.3 Si(OSiMe.sub.2).sub.p (OSiMeG).sub.r OSiMe.sub.3 VII
wherein R''' is a C.sub.1-10 alkyl group, Me is methyl, G is the group of Formula II, a has a value of 0 or 1, p has a value of at least 1, q has a value of 0 to 50 and r has a value of 1 to 50.

### Claim 6 (depends on 4)

A composition according to claim 4 comprising from 2% to 35% of nonionic surfactant and from 0.05% to 0.75% in total of polydimethylsiloxane foam-controller and siloxane-oxyalkylene copolymer dispersing agent in a weight ratio of foam-controller to dispersing agent from 8:1 to 12:1.

### Claim 7 (depends on 1)

A granular detergent composition according to claim 1 comprising:
(a) from 30% to 99% of base powder comprising:
(i) from 1% to 15% of organic surfactant selected from anionic, zwitterionic and ampholytic surfactants and mixtures thereof, and
(ii) from 5% to 98% of a detergency builder, and
(b) from 1% to 30% of a premix of alkoxylated nonionic surfactant, dispersed polydimethylsiloxane foam controller, and siloxane-oxyalkylene copolymer dispersing agent sprayed in fluent form onto at least a part of the base powder.

### Claim 8

A process for making a foam-controlled detergent composition comprising from 1.5% to 100% of a mixture of:
(a) alkoxylated nonionic surfactant,
(b) polydimethylsiloxane foam controller, and
(c) siloxane-oxyalkylene copolymer,
wherein the weight ratio of alkoxylated nonionic surfactant to polydimethylsiloxane foam controller is in the range from 10:1 to 100:1, and the weight ratio of polydimethylsiloxane foam controller to siloxane-oxyalkylene copolymer is in the range from 2:1 to 20:1, the process comprising forming a surfactant premix comprising at least part of the nonionic surfactant, the polydimethylsiloxane foam controller, and the siloxane-oxyalkylene copolymer and subjecting the premix in fluent form to high shear mixing.

### Claim 9 (depends on 8)

A process according to claim 8 comprising the steps of pre-mixing the alkoxylated nonionic surfactant and siloxane-oxyalkylene copolymer dispersing agent, admixing the polydimethylsiloxane foam controller with the surfactant/dispersing agent mixture, and thereafter subjecting the total mixture to high shear mixing.

### Claim 10 (depends on 1)

A foam-controlled detergent composition according to claim 1, in which the polydimethylsiloxane is dispersed in all of the alkoxylated nonionic surfactant.

### Claim 11 (depends on 10)

A foam-controlled detergent composition according to claim 10, in which the alkoxylated nonionic surfactant is condensation product of primary or secondary aliphatic alcohol having from 8 to 24 carbon atoms with from 2 to about 18 moles of alkylene oxide per mole of alcohol.

### Claim 12 (depends on 11)

A foam controlled detergent composition according to claim 11, in which the alkoxylated nonionic surfactant is ethoxylated primary C.sub.9-15 alcohol having an average degree of ethoxylation ranging from about 2 to 9.

### Claim 13 (depends on 1)

A foam-controlled detergent composition according to claim 1, in which the alkoxylated nonionic surfactant is condensation product of primary or secondary aliphatic alcohol having from 8 to 24 carbon atoms with from 2 to about 18 moles of alkylene oxide per mole of alcohol.

### Claim 14 (depends on 13)

A foam-controlled detergent composition according to claim 13 in which the alkoxylated nonionic surfactant is ethoxylated primary C.sub.9-15 alcohol having an average degree of ethoxylation ranging from about 2 to 9.

### Claim 15 (depends on 2)

A foam-controlled composition according to claim 2, in which the weight ratio of polydimethylsiloxane to silica is in the range from 25:1 to 100:1.

### Claim 16 (depends on 12)

A foam-controlled composition according to claim 12, in which the polydimethylsiloxane foam controller is dispersed in the nonionic surfactant together with particulate silica in a weight ratio of polydimethylsiloxane to silica in the range from 20:1 to 100:1.

### Claim 17 (depends on 16)

A foam-controlled composition according to claim 16, in which the siloxane-oxyalkylene copolymer is alkoxylated siloxane containing oxyethylene and oxypropylene groups.