# US 4,400,264 A · Process for the preparation of hydrocarbon oil distillates

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- Number: US 4,400,264 A
- Document ID: US4400264A
- Status: Granted
- Kind: A
- Application number: 06/429,778
- Filed: 1982-09-30
- Granted: 1983-08-23
- Earliest claimed: 1982-03-18
- Assignees: Shell Oil Company
- Inventors: Pieter B. Kwant; John R. Newsome
- Web page: https://patentgrep.com/patent/US4400264A

## CPC

- C10G 45/08: in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
- C10G 2300/107: Atmospheric residues having a boiling point of at least about 538 °C
- C10G: CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION (cracking to hydrogen or synthesis gas C01B; cracking or pyrolysis of hydrocarbon gases to individual hydrocarbons or mixtures thereof of definite or specified constitution C07C; cracking to cokes C10B); RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES

## Abstract

Distillates are prepared from asphaltenes-rich feeds by a process comprising subjecting the feed to thermal cracking, and subjecting the distillation residue of the cracked product to a combination of solvent deasphalting and catalytic hydroconversion.

## Claims

### Claim 1

A process for the production of hydrocarbon oil distillates from a hydrocarbon mixture feed stream containing asphaltenes, said process comprising:
(a) thermally cracking said feed stream and a deasphalted oil fraction in a thermal cracking zone into a first product stream containing less than 20 percent by weight C.sub.4 to C.sub.1 hydrocarbons;
(b) fractionating said first product stream into one or more light distillate fractions and a first heavy distillate fraction;
(c) catalytically hydrotreating said first heavy distillate fraction in a hydrotreating zone, therein producing a second product stream having a reduced asphaltenes content;
(d) fractionating said second product stream into one or more light distillate fractions and a second heavy distillate fraction;
(e) solvent deasphalting said second heavy distillate fraction in a deasphalting zone to obtain a deasphalted oil fraction and an asphaltic bitumen fraction; and
(f) routing said deasphalted oil fraction from step (e) to said thermal cracking zone.

### Claim 2

A process for the production of hydrocarbon oil distillates from a hydrocarbon mixture feed stream containing asphaltenes, said process comprising:
(a) thermally cracking said feed stream and a deasphalted oil fraction in a thermal cracking zone into a first product stream containing less than 20 percent by weight C.sub.4 to C.sub.1 hydrocarbons;
(b) fractionating said first product stream into one or more light distillate fractions and a first heavy distillate fraction;
(c) solvent deasphalting said first heavy distillate fraction in a deasphalting zone to obtain a deasphalted oil fraction and an asphaltic bitumen fraction;
(d) routing said deasphalted oil fraction to said thermal cracking zone;
(e) catalytically hydrotreating said asphaltic bitumen fraction in a hydrotreating zone, therein producing a second product stream having a reduced asphaltenes content;
(f) fractionating said second product stream into one or more light distillate fractions and a second heavy distillate fraction; and
(g) routing said second heavy distillate fraction to
(i) said deasphalting zone wherein said second heavy distillate fraction is solvent deasphalted,
(ii) said thermal cracking zone wherein said second heavy distillate fraction is thermally cracked, or
(iii) said deasphalting zone and said thermal cracking zone.

### Claim 3 (depends on 1, 2)

The process according to claim 1 or 2 wherein said feed stream is a hydrocarbon mixture which boils substantially above 350.degree. C., more than 35 percent by weight of which boils above 520.degree. C., and which has an RCT of more than 7.5 percent by weight.

### Claim 4 (depends on 1, 2)

The process according to claim 1 or 2 wherein said feed stream is a residue obtained in the vacuum distillation of an atmospheric distillation residue from a crude mineral oil.

### Claim 5 (depends on 1, 2)

The process according to claim 1 or 2 wherein said catalytic hydrotreating is carried out with a catalyst comprising at least one metal selected from the group consisting of nickel, cobalt and mixtures thereof and in addition, at least one metal selected from the group consisting of molybdenum, tungsten and mixtures thereof, deposited on a carrier, which carrier comprises more than 40% by weight alumina.

### Claim 6 (depends on 5)

The process according to claim 5 wherein said catalyst is selected from the group consisting of nickel/molybdenum on alumina and cobalt/molybdenum on alumina.

### Claim 7 (depends on 1, 2)

The process according to claim 1 or 2 wherein said catalytic hydrotreatment is carried out at a temperature of from 350.degree. to 450.degree. C., a pressure of from 75 to 200 bar, a space velocity of from 0.1 to 2 g.multidot.g.sup.-1 .multidot.hour.sup.-1 and a H.sub.2 /feed ratio of from 500 to 2000 Nl.multidot.kg.sup.-1.

### Claim 8 (depends on 1, 2)

The process according to claims 1 or 2 wherein said solvent deasphalting is carried out using n-butane as the solvent at a pressure of from 35 to 45 bar and a temperature of from 100.degree. to 150.degree. C.

### Claim 9 (depends on 1, 2)

The process according to claims 1 or 2 wherein said thermal cracking is carried out at a temperature of from 400.degree. to 525.degree. C. and a space velocity of from 0.01 to 5 kg feed per liter of cracking reactor volume per minute.